Selected English Publications (in PDF)

by G. B. Shul’pin

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REVIEWS: 

  1. A. E. Shilov, G. B. Shul’pin, “Activation of C–H Bonds by Metal Complexes”, Chem. Rev., 1997, 97, No. 8, 2879–2932. PDF

  2. G. B. Shul’pin,  "Metal-catalyzed hydrocarbon oxygenations in solutions: the dramatic role of additives: a review", J. Mol. Catal., A: Chem., 2002, 189, No. 1, 39–66. PDF.

  3. G. B. Shul’pin, "Metal-catalysed hydrocarbon oxidations", Comptes Rendus, Chimie, 2003, 6, No. 2, 163–178. PDF.

MONOGRAPHS

  1. A. E. Shilov, G. B. Shul’pin, “Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes”, Kluwer Academic Publishers, Dordrecht/Boston/London, 2000, (548 pp.) (URL of this book at Kluwer Academic Publishers: http://www.wkap.nl/book.htm/0-7923-6101-6).  See PDFs of pages 000-007, pages 008–020, pages 021–040, pages 041–075, pages 076–126, pages 127–155, pages 156–199, pages 200–218, pages 219–258, pages 259–317, pages 318–370, pages 371–429, pages 430–465, pages 466–522, pages 523–536. See also  a review by R. H. Crabtree in J. Am. Chem. Soc.,  a review by G. J. Leigh in J. Organometal. Chem., a review by  A. W. Parkins in Appl. Organometal. Chem., a review by H. H.  Kung in Appl. Catal. A: General.

  2. G. B. Shul’pin, "Oxidations of CH Compounds Catalyzed by Metal Complexes", in M. Beller, C. Bolm (Eds.), Transition Metals for Organic Synthesis, Wiley–VCH, Weinheim/New York, vol. 2 (chapter 2.2), 2nd edition, 2004, pp. 215–242. PDF.

ORIGINAL   PAPERS: 

  1. A. N. Nesmeyanov, G. B. Shul’pin, V. V. Krivykh, M. I. Rybinskaya, «Reduction of the double bond with molybdenum carbonyl», Doklady Chemistry, 1977, 232, Nos. 1–3, 26–27. PDF.

  2. A. N. Nesmeyanov, G. B. Shul’pin, M. V. Tolstaya, M. I. Rybinskaya, «Reduction of alpha-oxo and alpha-hydroxy derivatives of ferrocenophanes by sodium borohydride in the presence of a Lewis acid (aluminum chloride or boron trifluoride)», Doklady Chemistry, 1977, 232, Nos. 4–6, 96–98. PDF.

  3. G. B. Shul’pin, A. E. Shilov, A. N. Kitaigorodskii, J. V. Zeile Krevor, “The reaction of H2PtCl6 with aromatic compounds affording the sigma-aryl complexes of Pt(IV). II. The synthesis of Pt(IV) complexes of benzene, alkylbenzenes and chlorinated benzenes”, J. Organometal. Chem., 1980, 201, 319–325. PDF.

  4. G. B. Shul’pin, “The reaction of H2PtCl6 with aromatic compounds affording the sigma-aryl complexes of Pt(IV). III. The synthesis of Pt(IV) complexes of benzenes containing electron-withdrawing substituents”, J. Organometal. Chem., 1981, 212, 267–274. PDF

  5. G. B. Shul’pin, A. N. Kitaigorodskii, “The reaction of H2PtCl6 with aromatic compounds affording the sigma-aryl complexes of Pt(IV). IV. The synthesis of Pt(IV) complexes of fluorinated benzenes and the electronic influence of the platinum moiety”, J. Organometal. Chem., 1981, 212, 275–281. PDF.

  6. R. P. Shibaeva, L. P. Rozenberg, R. M. Lobkovskaya, A. E. Shilov, G. B. Shul’pin, “The crystal and molecular structures of Pt(IV) complexes of naphthalene and o-nitrotoluene <Part V from the series “The reaction of H2PtCl6 with aromatic compounds affording the sigma-aryl complexes of Pt(IV)””, J. Organometal. Chem., 1981, 220, 271–276.  PDF .

  7. G. B. Shul’pin,  «Reaction of aromatic compounds with H2PtCl6 in CF3COOH–H2O system leading to the preparation of anionic sigma-aryl complexes of Pt(IV)», J. Gen. Chem. USSR, 1981, 51, No. 9, Part 2, 1808–1818. PDF.

  8. G. B. Shul’pin, “Reduction of carbonyl group to methylene group in ferrocene and ruthenocene derivatives by sodium borohydride in the presence of protonic and Lewis acids”, J. Gen. Chem. USSR, 1981, 51, No. 9, Part 2, 1854. PDF.

  9. G. B. Shul’pin, G. V. Nizova,  «Formation of sigma-aryl complexes of platinum(II) in the reaction of  aromatic compounds with salts of Pt(II) and their oxidation under the action of  H2PtCl6», Kinetics and Catalysis, 1981, 22, No. 4, Part 2, 834–836. PDF.

  10. G. V. Nizova, G. B. Shul’pin, “Arylation of olefins by phenyl derivatives of nontransition metals in presence of platinum(IV) and gold(III) complexes”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1981, 30, No. 11, Part 2, 2211. PDF.

  11. G. B. Shul’pin, P. Lederer, G. V. Nizova, “Formation of sigma-aryl complexes of platinum(IV) in the reactions of H2PtCl6 with phenylboronic acid and with the tetraphenylborate ion. Arylation of olefins with phenyl derivatives of boron”, J. Gen. Chem USSR, 1982, 52, No. 6, Part 2, 1262. PDF.

  12. G. V. Nizova, J. V. Z. Krevor, A. N. Kitaigorodskii, G. B. Shul’pin, “Isolation of platinum(II) pi-olefin complexes formed by the reaction of saturated hydrocarbons with H2PtCl6 in CF3COOH–H2O solution”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1982, 31, No. 12, Part 2, 2480–2482. PDF.

  13. G. B. Shul’pin, G. V. Nizova, A. E. Shilov, “Photoinduced reactions of PtCl6 with saturated hydrocarbons and other C–H containing compounds” J. Chem. Soc., Chem. Commun., 1983, 671–672. PDF.

  14. G. B. Shul’pin, G. V. Nizova,  “Synthesis of Pt(II) pi-olefin complexes by reaction of  Na2PtCl6 or  Na2PtCl4 in acetone using light irradiation”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1983, 32, No. 3, Part 2, 607–608. PDF.

  15. G. V. Nizova, P. Lederer, G. B. Shul’pin, “Oxidative coupling of arenes or aryl derivatives with olefins under the action of Pt(IV) compounds” Oxid. Commun., 1983, 4, Nos. 1–4, 131–135. PDF.

  16. N. Zilkova, G. B. Shul’pin, P. Lederer, “Photochemical oxidation of ethylbenzene and other hydrocarbons in the presence of Co(III) 2,4-pentadionate”, Coll. Czech. Chem. Commun., 1984, 49, 2376–2381. PDF.

  17. M. V. Serdobov, G. V. Nizova, G. B. Shul’pin, “Formation of organometallic complexes of Pt(II) and Pt(IV) in reactions of PtCl6 with alkanes, olefins and aromatics induced by gamma-irradiation” J. Organometal. Chem., 1984, 265, C12–C14. PDF.

  18. V. V. Zamaschchikov, E. S. Rudakov, S. A. Mitchenko, G. V. Nizova, A. N. Kitaigorodskii, G. B. Shul’pin,  “Formation of the sigma-acetonyl Pt(IV) complex in the reaction of iodoacetone with PtCl4  in aqueous solution”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1984, 33, No. 7, Part 2, 1520–1522. PDF.

  19. G. B. Shul’pin, G. V. Nizova,  A. E. Shilov, A. T. Nikitaev, M. V. Serdobov, “Photoinduced reactions of organic compounds with transition metal complexes. Communication 1. First example of substitution in the aromatic nucleus in photoexcitation of an electrophilic reagent: formation of sigma-aryl complexes of Pt(IV) in the reaction of  PtCl6  with arenes”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1984, 33, No. 12, Part 1, 2454–2459. PDF.

  20. G. V. Nizova, M. V. Serdobov, A. T. Nikitaev, G. B. Shul’pin, “Photoinduced reactions of organic compounds with transition metal complexes. II. Reaction of PtCl6 with acetone to give a sigma-acetonyl complex of Pt(IV). Detection of Pt(III) compounds by ESR”, J. Organometal. Chem., 1984, 275, 139–144. PDF.

  21. G. B. Shul’pin, G. V. Nizova, A. N. Kitaigorodskii, M. V. Serdobov, “Photoinduced reactions of organic compounds with transition metal complexes. III. Formation of a sigma-methyl complex of Pt(IV) and a pi-ethylene complex of Pt(II) in photochemical and thermal reactions of PtCl62–- with methyl and ethyl derivatives of tin or germanium. Thermal oxidative addition of Me4Sn to PtCl4 to afford the sigma-methyl complex of Pt(IV)”, J. Organometal. Chem., 1984, 275, 273–282. PDF.

  22. G. B. Shul’pin, G. V. Nizova, P. Lederer, “Photoinduced reactions of organic compounds with transition metal complexes. IV. Thermal and photochemical reactions of PtCl6 and PtCl4 with olefins and alcohols: convenient synthesis of pi-olefin complexes of Pt(II)”, J. Organometal. Chem., 1984, 275, 283–294. PDF.

  23. A. N. Kitaigorodskii, V. M. Nekipelov, A. T. Nikitaev, G. B. Shul’pin, “The reaction of PtCl6 with aromatic compounds to afford anionic sigma-aryl complexes of Pt(IV). VI. The 195Pt and 13C NMR spectra of sigma-aryl complexes”, J. Organometal. Chem., 1984, 275, 295–301. PDF.

  24. G. B. Shul’pin, G. V. Nizova, “The reaction of PtCl6 with aromatic compounds to afford anionic sigma-aryl complexes of Pt(IV). VII. Cleavage of aryl-element bonds (element = Hg, Sn, Pb or B). Arylation reactions of arenes and olefins with aryl complexes of Pt(IV)”, J. Organometal. Chem., 1984, 276, 109–114. PDF.

  25. G. B. Shul’pin, G. V. Nizova, A. T. Nikitaev, “The reaction of PtCl6 with aromatic compounds to afford anionic sigma-aryl complexes of Pt(IV). VIII. Kinetics and mechanisms of thermal, photochemical and gamma-induced reactions with arenes and arylmercury compounds (electrophilic substitution involving electron transfer)”, J. Organometal. Chem., 1984, 276, 115–153. PDF

  26. G. B. Shul’pin, G. V. Nizova, A. T. Nikitaev, “Photoinduced reactions of organic compounds with complexes of transition metals. V. Formation of a pi-olefin complex of Pt(II) in the reaction of hexane with PtCl6 in CH3COOH under the action of light”, J. Gen. Chem. USSR, 1985, 55, No. 6, Part 2, 1251–1256. PDF.

  27. G. B. Shul’pin, P. Lederer, G. V. Nizova, M. V. Serdobov, “Photoinduced reactions of organic compounds with complexes of transition metals. VI. Reduction of the PtCl6 ion with carbon monoxide under the action of light”, J. Gen. Chem. USSR, 1986, 56, No. 11, Part 2, 2316–2317. PDF.

  28. V. V. Zamashchikov, E. S. Rudakov, S. A. Mitchenko, G. V. Nizova, A. N. Kitaigorodskii, G. B. Shul’pin, “Intermediate formation of an ethyl complex of platinum in the system EtI–PtCl4–H2O”, Bull. Acad. Sci. USSR. Div. Chem. Sci., 1986, 35, No. 1, Part 2, 175–178. PDF.

  29. G. V. Nizova,  G. B. Shul’pin, “Reaction of sterically hindered arylmercury compounds with Pt(IV), Pt(II), and Pd(II) chloride complexes”, Bull. Acad. Sci. USSR. Div. Chem. Sci., 1986, 35, No. 10, Part 2, 2174–2176. PDF.

  30. G. B. Shul’pin, G. V. Nizova,  “Reduction of tolan to stilbene by sodium borohydride catalyzed by rhodium complexes”, Bull. Acad. Sci. USSR. Div. Chem. Sci., 1986, 35, No. 10, Part 2, 2176–2177. PDF.

  31. G. B. Shul’pin, A. E. Shilov, G. V. Nizova, A. K. Yatsimirskii, S. A. Deiko, P. Lederer, “Isomeric composition of ditolyls formed upon the thermal decomposition of an anionic Pt(IV) sigma-tolyl chloride complex”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986, 35, No. 10, Part 2, 2177–2179. PDF

  32. G. B. Shul’pin, P. Lederer, E. Macova, “Photooxidation of hydrocarbons by chromium(VI) oxo compounds”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986, 35, No. 11, Part 2, 2422. PDF.

  33. G. B. Shul’pin, P. Lederer, E. Macova, “Photooxidation of hydrocarbons by chromium(VI) oxo compounds”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986, 35, No. 11, Part 2, 2422. PDF.

  34. G. V. Nizova, G. B. Shul’pin, “Oxidation of mesitylene by  PtCl6  ions in trifluoroacetic acid”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1987, 36, No. 4, Part 2, 862–863. PDF.

  35. G. V. Nizova, G. B. Shul’pin, “Reactions of 2,4-dimethylphenylmercury and pentamethylphenylmercury acetates with olefins in the presence of Pd(II) and Pt(IV) complexes”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1987, 36, No. 9, Part 2, 1920–1921. PDF.

  36. G. B. Shul’pin, G. V. Nizova, M. V. Serdobov, “Photoinduced reactions of organic compounds with complexes of transition metals. VII. Photochemical oxidative coupling of arenes under the action of chloride complexes of Os(IV), Ir(IV), and Rh(III)”, J. Gen. Chem. USSR, 1987, 57, No. 2, Part 2, 402–404. PDF.

  37. G. B. Shul’pin, P. Lederer, Yu. V. Geletii, “Photoinduced reactions of organic compounds with complexes of transition metals. VIII. Photochemical chlorination of saturated and aromatic hydrocarbons with AuCl4–complex”, J. Gen. Chem. USSR, 1987, 57, No. 3, Part 2, 543–548. PDF.

  38. G. B. Shul’pin, G. V. Nizova, Yu. V. Geletii, “Photoinduced reactions of organic compounds with complexes of transition metals. IX. Oxidation of hexane and other alkanes and isomerization of 2-hexene under the influence of the PtCl6 ion in CF3COOH”, J. Gen. Chem. USSR, 1987, 57, No. 3, Part 2, 548–552.

  39. PDF.
  40. G. B. Shul’pin, M. M. Kats, G. V. Nizova, “Photooxidation of alkylbenzenes and cyclohexane by atmospheric oxygen in acetonitrile sensitized by o-phenanthroline”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1988, 37, No. 11, Part 2, 2395. PDF.

  41. G.B.Shul’pin, M.M.Kats, Yu.N.Kozlov, “Oxidation of benzene and alkylbenzenes by xenone trioxide catalyzed by Cr(VI) oxo compounds or Mn and Fe porphyrin complexes”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1988, 37, No. 11, Part 2, 2396.

  42. PDF.
  43. G.B.Shul’pin, A.N.Druzhinina, “Oxidation of ethylbenzene by atmospheric oxygen and iodosobenzene catalyzed by CrO3”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989, 37, No. 5, Part 2, 1079–1081. PDF.

  44. G. B. Shul’pin, M. M. Kats, “Photocatalytic oxidation of cyclohexane by atmospheric oxygen in CH2Cl2 in the presence of an oxometallate-tetraalkylammonium system”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989, 38, No. 10, Part 2, 2202. PDF.

  45. G. V. Nizova, G. B. Shul’pin, “Oxidation of alkanes by atmospheric oxygen in CH3CN or CH2Cl2 catalyzed by AuCl4– ions upon light irradiation”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989, 38, No. 10, Part 2, 2205. PDF.

  46. G. B. Shul’pin, E. Macova, P. Lederer, “Photoinduced reactions of organic compounds with transition-metal complexes. X. Oxidation of alkanes and alkyl benzenes by Cr(VI) oxo compounds on exposure to light”, J. Gen. Chem. USSR, 1989, 59, No. 11, Part 2, 2329–2334. PDF.

  47. G. B. Shul’pin, A. N. Kitaigorodskii, “Photoinduced reactions of organic compounds with transition-metal complexes. XI. Relative rates of oxidation of the methyl group in substituted toluenes by Cr(VI) oxo compounds in thermal and photochemical reactions”, J. Gen. Chem. USSR, 1989, 59, No. 11, Part 2, 2335–2337. PDF.

  48. G. B. Shul’pin, M. M. Kats, “Photoinduced reactions of organic compounds with transition-metal complexes. XII. Oxidation of toluene to benzaldehyde by oxygen in the presence of the Cr(VI)–(C4H9)4N+ system”, J. Gen. Chem. USSR, 1989, 59, No. 11, Part 2, 2338–2340. PDF.

  49. G. B. Shul’pin, M. M. Kats, “Photoinduced reactions of organic compounds with transition-metal complexes. XIII. Oxidation of alkylbenzenes with oxygen catalyzed by polyoxometalate ions”, J. Gen. Chem. USSR, 1989, 59, No. 12, Part 2, 2447–2450. PDF.

  50. G. B. Shul’pin, M. M. Kats, P. Lederer, “Photoinduced reactions of organic compounds with transition-metal complexes. XIV. Photooxidation of toluene to benzaldehyde with oxygen in CH3COOH catalyzed by FeCl3 and phenanthroline”, J. Gen. Chem. USSR, 1989, 59, No. 12, Part 2, 2450–2455.

  51.   PDF.
  52. A. N. Druzhinina, G. V. Nizova, G. B. Shul’pin, “Hydrogen peroxide oxidation of hydrocarbons catalyzed by Cr(VI) oxo compounds”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990, 39, No. 1, Part 2, 194–195. PDF.

  53. G. B. Shul’pin, A. N. Druzhinina, G. V. Nizova, “Photooxidation of cyclohexane by (Bu4N)2Cr4O13 in acetonitrile or CH2Cl2”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990, 39, No. 1, Part 2, 195–196. PDF.

  54. G. V. Nizova, M. M. Kats, G. B. Shul’pin, “Photooxidation of alkanes by oxygen catalyzed by CuCl2 in acetonitrile”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990, 39, No. 3, Part 2, 618–619.

  55. PDF.
  56. M. M. Kats, G. B. Shul’pin, “Photooxidation of alkanes and benzene by polyvanadate in CF3COOH”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990, 39, No. 10, Part 2, 2233. PDF.

  57. G. B. Shul’pin, A. N. Kitaigorodskii, “Oxidation of substituted toluenes by oxygen in the presence of Fe or Cu powder”, J. Gen. Chem. USSR, 1990, 60, No. 5, Part 1, 920–921. PDF.

  58. G. B. Shul’pin, M. M. Kats, “Ferric chloride catalyzed photooxidation of alkanes by air in organic solvents”, React. Kinet. Catal. Lett., 1990, 41, No. 2, 239–243. PDF.

  59. G. B. Shul’pin, G. V. Nizova, “Photoinduced reactions of organic compounds with transition-metal complexes. XV. Photooxidation of alkylaromatic and saturated hydrocarbons by air in CH3COOH in the presence of AuCl4– or PtCl6”, J. Gen. Chem. USSR, 1990, 60, No. 9, Part 2, 1892–1894. PDF.

  60. G. V. Nizova, G. B. Shul’pin, “Photoinduced reactions of organic compounds with transition-metal complexes. XVI. Air oxidation of alkylaromatic and saturated hydrocarbons sensitized by UO22+”, J. Gen. Chem. USSR, 1990, 60, No. 9, Part 2, 1895–1896. PDF.

  61. G. B. Shul’pin, G. V. Nizova, M. M. Kats, “Photoinduced reactions of organic compounds with transition-metal complexes. XVII. Oxidation of saturated and arylalkane hydrocarbons with atmospheric oxygen photosensitized with metal chlorides”, J. Gen. Chem. USSR, 1990, 60, No. 12, Part 2, 2447–2449.

  62. PDF.
  63. G. B. Shul’pin, M. M. Kats, “Photoinduced reactions of organic compounds with transition-metal complexes. XVIII. Oxidation of saturated and alkylaromatic compounds by CrO3 in acetonitrile on irradiation”, J. Gen. Chem. USSR, 1991, 61, No. 3, Part 2, 684–685.

  64. PDF.
  65. G. B. Shul’pin, M. M. Kats, “Photochemical oxidation of saturated and alkylaromatic hydrocarbons by atmospheric oxygen in CH3CN or CH2Cl2 solution, catalysed by iron(III) halides <Report XX from series “Photoinitiated reactions of organic compounds with metal complexes””, Petrol.Chem. 1991, 31, No. 5, 647–656. PDF.

  66. G. B. Shul’pin, G. V. Nizova, M. M. Kats, “Oxidation of alkanes and arylalkanes in solutions by atmospheric oxygen during light irradiation, catalysed by copper halides <Report XXI from series “Photoinitiated reactions of organic compounds with metal complexes”” Petrol. Chem. 1991, 31, No. 5, 657–665. PDF.

  67. G. B. Shul’pin, A. N. Druzhinina, G. V. Nizova, “Photoinduced reactions of organic compounds with transition metals. 22. Polychromate-catalyzed photooxygenation of alkanes and other compounds by O2 or air in CH2Cl2” Bull. Acad. Sci. USSR, Div. Chem. Sci., 1991, 40, No. 11, Part 1, 2145–2149.

  68. PDF.
  69. G. V. Nizova, G. B. Shul’pin, “Photooxygenation of saturated and alkylaromatic hydrocarbons, catalysed by platinum metal halides <Report XXIII from series “Photoinitiated reactions of organic compounds with transition metal complexes””, Petrol.Chem., 1991, 31, No. 6, 829–835. PDF.

  70. A. N. Druzhinina, L. S. Shul’pina, G. B. Shul’pin, “Photochemical oxidation of hydrocarbons by atmospheric oxygen in acetonitrile catalyzed by cyclopentadienyliron complexes”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1991, 40, No. 7, Part 2, 1492–1494. PDF.

  71. G. B. Shul’pin, S. A. Deiko, A. K. Yatsimirskii, “Oxidation of toluene by the PtBr6 ion in CF3COOH–H2O solution”, J. Gen. Chem. USSR, 1991, 61, No. 4, Part 1, 742–744. PDF.

  72. A. N. Druzhinina, G. B. Shul’pin, “Biomimetic activation of the C–H bond. 1. Oxygenation of hydrocarbons by atmospheric oxygen in the presence of metal chlorides and ascorbic acid or glucose”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1991, 40, No. 7, Part 1, 1317–1320. PDF.

  73. G. B. Shul’pin, A. N. Druzhinina, “Biomimetic activation of the C–H bond. 2. Oxygenation of hydrocarbons with O2 catalyzed by porphyrin complexes of metals in the presence of ferrocene as reducing agent”, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1991, 40, No. 12, Part 1, 2385–2389. PDF.

  74. M. M. Kats, Yu. N. Kozlov, G. B. Shul’pin, “Oxidation of benzene and cyclohexane in CH3CN–H2O by means of XeO3 and XeF2”, J. Gen. Chem. USSR, 1991, 61, No. 8, Part 2, 1694–1696. PDF.

  75. G. B. Shul’pin, A. N. Druzhinina, “Molybdenum hexacarbonyl catalyzed photooxygenation of cyclohexane by air oxygen in CH3CN solution”, React. Kinet. Catal. Lett., 1991, 44, No. 2, 387–391. PDF.

  76. G. B. Shul’pin, G. V. Nizova, “Contribution of air oxygen to photooxidation of alkanes by V(V) and Cr(VI) oxocomplexes”, React. Kinet. Catal. Lett., 1991, 45, No. 1, 7–14.

  77.   PDF.
  78. G. V. Nizova, G. V. Losenkova, G. B. Shul’pin, “Unusual selectivity in photooxygenation of alkanes by air in CH3CN solutions catalyzed by CrCl3–C6H5CH2N(C2H5)3Cl”, React. Kinet. Catal. Lett., 1991, 45, No. 1, 27–34. PDF .

  79. G. V. Nizova, J. Muzart, G. B. Shul’pin, “Cyclohexane photooxygenation by air oxygen in CH2Cl2 in the presence of   chromium oxocomplex–iodosylbenzene system”,  React. Kinet. Catal. Lett., 1991, 45, No. 2, 173–178.

  80. PDF.
  81. P.Lederer, G. V. Nizova, M. M. Kats, G. B. Shul’pin, “Photooxygenation of cyclohexane by dioxygen in the presence of metal chlorides in acetonitrile <Part XIX in the series “Photoinduced Reactions of Organic Compounds with Transition Metal Complexes””, Coll. Czech. Chem. Commun., 1992, 57, 107–112.

  82. PDF.
  83. G. B. Shul’pin, A. N. Druzhinina, “Iron(III) chloride catalysed photooxygenation of alcohol solutions of alkanes by atmospheric oxygen”, Mendeleev Commun., 1992, No. 1, 36–37. PDF.

  84. G. V. Nizova, G. B. Shul’pin, “Photochemical oxidation of hydrocarbons by atmospheric oxygen in solutions, catalysed by AuCl4– complex <Report XXIV from series “Photoinitiated reactions of organic compounds with transition metal complexes”” Petrol. Chem., 1992, 32, No. 1, 36–41. PDF.

  85. J. Muzart, G. V. Nizova, A. Riahi, G. B. Shul’pin, “Oxidation of alkanes by peroxide complexes of palladium”, J. Gen. Chem., 1992, 62, No. 5, 964. PDF.

  86. G. B. Shul’pin, A. N. Druzhinina, “Photooxidation of cyclohexane by atmospheric oxygen in 2-propanol or methanol catalyzed by FeCl3”, Bull. Russ. Acad. Sci., Div. Chem. Sci., 1992, 41, No. 2, Part 2, 346–347.

  87. PDF.
  88. G. V. Nizova, B. Chaudret, Xiao-Dong He, G. B. Shul’pin, “Photochemical dehydrogenation of cyclohexane and its derivatives by the cyclopentadienyl complexes of ruthenium with the formation of pi-arene complexes of ruthenium(II)”, Bull. Russ. Acad. Sci., Div. Chem. Sci., 1992, 41, No. 6, Part 2, 1138. PDF .

  89. D. Attanasio, L. Suber, G. B. Shul’pin, “Photochemical oxidation of hydrocarbons by a vanadium(V) peroxo complex”, Bull. Russ. Acad. Sci., Div. Chem. Sci., 1992, 41, No. 8, Part 2, 1502–1504. PDF .

  90. G. B. Shul’pin, A. N. Druzhinina, “Hydroperoxidation of alkanes by atmospheric oxygen in the presence of hydroquinone or quinone catalyzed by copper(II) acetate under visible light irradiation”, React. Kinet. Catal. Lett., 1992, 47, No. 2, 207–211.

  91. PDF.
  92. G. B. Shul’pin, G. V. Nizova, “Formation of alkyl peroxides in oxidation of alkanes by H2O2 catalyzed by transition metal complexes” React. Kinet. Catal. Lett., 1992, 48, No. 1, 333–338. PDF .

  93. G. B. Shul’pin, D. Attanasio, L. Suber, “Efficient H2O2 oxidation of alkanes and arenes to alkyl peroxides and phenols catalyzed by the system vanadate–pyrazine-2-carboxylic acid”, J. Catal., 1993, 142, 147–152. PDF .

  94. G. B. Shul’pin, D. Attanasio, L. Suber, “Oxidations by a H2O2–VO3––pyrazine-2-carboxylic acid reagent. 1. Oxidations of alkanes in CH3CN to produce alkyl peroxides”, Russ. Chem. Bull., 1993, 42, No. 1, 55–59. PDF .

  95. G. B. Shul’pin, A. N. Druzhinina, G. V. Nizova, “Oxidation with the H2O2–VO3–– pyrazine-2-carboxylic acid reagent. 2. Oxidation of alcohols and aromatic hydrocarbons”, Russ. Chem. Bull., 1993, 42, No. 8, 1327–1329. PDF .

  96. G. B. Shul’pin, G. V. Nizova, “Photo-oxidation of cyclohexane by atmospheric oxygen in acetonitrile, catalysed by chloride complexes of iron, copper and gold <Report XXV from series “Photoinitiated reactions of organic compounds with metal complexes”” Petrol. Chem., 1993, 33, No. 2, 107–112. PDF.

  97. J. Muzart, A. N. Druzhinina, G. B. Shul’pin, “Photooxygenation of cyclohexane with air oxygen in methylene chloride catalyzed by an oxo complex of chromium(IV) <Report XXV from series “Photoinitiated reactions of organic compounds with metal complexes””, Petrol. Chem., 1993, 33, No. 2, 113–115. PDF.

  98. G. B. Shul’pin, A. N. Druzhinina, «Oxidation of saturated hydrocarbons by air in acetonitrile in the presence of molybdenum or tungsten carbonyls during light irradiation) <Report XXVII from series “Photoinitiated reactions of organic compounds with metal complexes”», Petrol. Chem., 1993, 33, No. 3, 247–251. PDF .

  99. G. B. Shul’pin, A. N. Druzhinina, L. S. Shul’pina, “Photo-oxidation of cyclohexane by air in acetonitrile, catalysed by pi-complexes of iron <Report XXVIII from series “Photoinitiated reactions of organic compounds with metal complexes””, Petrol. Chem.,  1993, 33, No. 4, 321–325. PDF.

  100. G. Süss-Fink, G. B. Shul’pin, “The oxidation of alkanols with air oxygen in the catalytic system copper(II) acetate–hydroquinone promoted by visible light”, Russ. Chem. Bull., 1994, 43, No. 6, 1085–1086. PDF.

  101. G. V. Nizova, G. B. Shul’pin, “Oxidation by a H2O2–vanadium complex–2-pyrazinecarboxylic acid reagent. 3. Evidence for hydroxyl radical formation”, Russ. Chem. Bull., 1994, 43, No. 7, 1146–1148. Full PDF .

  102. J. Vicente, A. Arcas, D. Bautista, G. B. Shul’pin, “Aerobic photooxidation and C–C bond cleavage of the acetylacetonate ligand in (2-arylazo)arylpalladium(II) complexes induced by visible light”, J. Chem. Soc., Dalton Trans., 1994, No. 10, 1505–1509. PDF.

  103. G. V. Nizova, G. B. Shul’pin, “Photo-oxidation of alkanes by atmospheric oxygen, catalysed a vanadate–anthraquinone system <Report XXIX from series “Photoinitiated reactions of organic compounds with metal complexes””, Petrol. Chem., 1994, 34, No. 4, 353–356. PDF.

  104. G. B. Shul'pin, G. Süss-Fink «Oxidations by the reagent “H2O2– vanadium complex–pyrazine-2-carboxylic acid”.  Part 4. Oxidation of alkanes, benzene and alcohols by an adduct of H2O2 with urea», J. Chem. Soc., Perkin Trans. 2, 1995, No. 7, 1459–1463. PDF

  105. G. B. Shul’pin, M. M. Bochkova, G. V. Nizova, «Aerobic oxidation of saturated hydrocarbons into alkyl hydroperoxides induced by visible light and catalysed by a “quinone–copper acetate” system <Part 30 of the series “Photoinduced Reactions of Organic Compounds with Transition Metal Complexes”», J. Chem. Soc., Perkin Trans. 2, 1995, No. 7, 1465–1469. PDF .

  106. G. B. Shul’pin, G. V. Nizova, “Selective photochemical ketonization of cyclohexane by air in aqueous emulsion in the presence of iron ions”, Mendeleev Commun., 1995, No. 4, 143–145. PDF.

  107. C. Vicente, G. B. Shul’pin, B. Moreno, S. Sabo-Etienne, B. Chaudret, “Reduction of ketones by dihydrogen or hydrogen transfer catalysed by a ruthenium complex of the hydridotris(3,5-dimethyl)pyrazolyl borate ligand”, J. Mol. Catal., A: Chem., 1995, 98, L5–L8. PDF.

  108. G. V. Nizova, G. B. Shul’pin, “Alkane aerobic photo-oxygenation sensitized by pyrazine derivatives”, Russ. Chem. Bull., 1995, 44, No. 10, 1982–1983.

  109. PDF.
  110. G. B. Shul’pin, M. C. Guerreiro, U. Schuchardt, “Oxidations by the reagent O2–H2O2–vanadium complex–pyrazine-2-carboxylic acid. Part 7. Hydroperoxidation of higher alkanes”, Tetrahedron, 1996, 52, No 41, 13051–13062. PDF .

  111. G. V. Nizova, G. B. Shul’pin, “Aerobic oxidation of cumene photocatalyzed by iron salts”, Russ. Chem. Bull., 1996, 45, No 6, 1353–1355. PDF.

  112. U. Schuchardt, D. Mandelli, G. B. Shul’pin, “Methyltrioxorhenium catalyzed oxidation of saturated and aromatic hydrocarbons by H2O2 in air”, Tetrahedron Lett., 1996, 37, No 36, 6487–6490. PDF.

  113. G. B. Shul’pin, R. S. Drago, M. Gonzalez, “Oxidations by a “H2O2–vanadium complex–pyrazine-2-carboxylic acid” reagent.  5. Oxidation of lower alkanes with the formation of carbonyl compounds”, Russ. Chem. Bull., 1996, 45, No. 10, 2386–2388. PDF.

  114. G. B. Shul’pin, G. V. Nizova, Yu. N. Kozlov, «Photochemical aerobic oxidation of alkanes promoted by iron complexes <Part 32 of the series “Photoinduced Reactions of Organic Compounds with Metal Complexes”», New J. Chem., 1996, 20, No 12, 1243–1256. PDF.

  115. M. C. Guerreiro, U. Schuchardt, G. B. Shul’pin, “Oxidations by the reagent O2–vanadium complex–pyrazine-2-carboxylic acid. Part 6. Oxidation of n-heptane. Direct GLC detection of formed alkyl hydroperoxides”, Russ. Chem. Bull., 1997, 46, No 4, 749–754. PDF.

  116. G. V. Nizova, G. Süss-Fink, G. B. Shul’pin, “Oxidations by the reagent «O2–H2O2–vanadium complex–pyrazine-2-carboxylic acid» – 8. Efficient oxygenation of methane and other lower alkanes in acetonitrile”, Tetrahedron, 1997, 53, No. 10, 3603–3614. PDF

  117. G. B. Shul’pin, M. M. Bochkova, G. V. Nizova, N. B. Kozlova, “Aerobic photodegradation of phenols in aqueous solutions promoted by metal compounds”, Appl. Catal., B: Environmental, 1997, 12, No. 1, 1–19. PDF.

  118. G. V. Nizova, G. Süss-Fink, G. B. Shul’pin, “Catalytic oxidation of methane to methyl hydroperoxide and other oxygenates under mild conditions”, Chem. Commun., 1997, 397–398. PDF.

  119. G. Süss-Fink, Hong Yan, G. V. Nizova, S. Stanislas, G. B. Shul’pin,“Oxygenation of methane with atmospheric oxygen in aqueous solution promoted by H2O2 and catalyzed by a vanadate ion–pyrazine-2-carboxylic acid system”, Russ. Chem. Bull., 1997, 46, No. 10, 1801–1803. PDF.

  120. U. Schuchardt, M. C. Guerreiro, G. B. Shul’pin, «Oxidation with the ‘O2–H2O2–vanadium complex–pyrazine-2-carboxylic acid’ reagent. 9. Oxidation of cyclohexene and decalin», Russ. Chem. Bull., 1998, 47, No. 2, 247–252. PDF.

  121. G. Süss-Fink, G. V. Nizova, S. Stanislas, G. B. Shul’pin, «Oxidations by the reagent ‘O2–H2O2–vanadate anion–pyrazine-2-carboxylic acid’. Part 10. Oxygenation of methane in acetonitrile and water», J. Mol. Catal., A: Chem., 1998, 130, No. 1–2, 163–170. PDF .

  122. J. R. Lindsay Smith, G. B. Shul’pin, “Efficient stereoselective oxygenation of alkanes by peroxyacetic acid or hydrogen peroxide and acetic acid catalysed by a manganese(IV) 1,4,7-trimethyl-1,4,7-triazacyclononane complex”, Tetrahedron Lett., 1998, 39, No. 27, 4909–4912. PDF.

  123. J. R. Lindsay-Smith, G. B. Shul’pin, “Oxidative decarboxylation of cyclohexanecarbaldehyde in the presence of cyclooctane catalyzed by a binuclear manganese(IV) complex”, Russ. Chem. Bull., 1998, 47, No. 11, 2313–2315.

  124. PDF.
  125. G. B. Shul’pin, J. R. Lindsay-Smith, «Oxidations by the reagent ‘H2O2–manganese(IV) complex–carboxylic acid’. Part 1. Oxidation of saturated hydrocarbons with peroxy acids and hydrogen peroxide», Russ. Chem. Bull., 1998, 47, No. 12, 2379–2386. PDF .

  126. G. V. Nizova, G. Süss-Fink, S. Stanislas, G. B. Shul’pin, “Carboxylation of methane with CO or CO2 in aqueous solution catalysed by vanadium complexes”, Chem. Commun., 1998, 1885–1886. PDF .

  127. G. B. Shul’pin, G. Süss-Fink, J. R. Lindsay Smith, «Oxidations by the system “Hydrogen Peroxide–Manganese(IV) Complex–Acetic Acid”, Part II. Hydroperoxidation and hydroxylation of alkanes in acetonitrile», Tetrahedron, 1999, 55, No. 17, 5345–5358. PDF.

  128. G. B. Shul’pin Y. Ishii, S. Sakaguchi, T. Iwahama, «Oxidations with the “O2–H2O2–vanadium complex–pyrazine-2-carboxylic acid” reagent. Part 11. Oxidation of styrene, phenylacetylene, and their derivatives with the formation of benzaldehyde and benzoic acid», Russ. Chem. Bull., 1999, 48, No. 5, 887–890. PDF.

  129. G. Süss-Fink, S. Stanislas, G. B. Shul’pin, G. V. Nizova, H. Stoeckli-Evans, A. Neels, C. Bobillier, S. Claude, “Oxidative functionalisation of alkanes: synthesis, molecular structure and catalytic implications of anionic vanadium(V) oxo and peroxo complexes containing bidentate N,O ligands”, J. Chem. Soc., Dalton Trans., 1999, No. 18, 3169–3175. PDF .

  130. G. B. Shul’pin, G. Süss-Fink, L. S. Shul’pina, “Oxygenation of alkanes with hydrogen peroxide catalysed by osmium complexes”, Chem. Commun., 2000, No. 13, 1131–1132.  Full PDF.

  131. G. Süss-Fink, S. Stanislas, G. B. Shul’pin, G. V. Nizova, “Catalytic functionalisation of methane”, Appl. Organometal. Chem., 2000, 14, 623–628. PDF

  132. G. B. Shul’pin, G. Süss-Fink, L. S. Shul’pina, “Oxidative functionalisation of ethane with hydrogen peroxide catalysed by chromic acid”, J. Chem. Res. (S), 2000, No. 12, 576–577. PDF.

  133. G. B. Shul’pin, G. Süss-Fink, L. S. Shul’pina, «Oxidations by the system "hydrogen peroxide–manganese(IV) complex–carboxylic acid" Part 3. Oxygenation of ethane, higher alkanes, alcohols, olefins and sulfides», J. Mol. Catal., A: Chem., 2001, 170, No. 1–2, 17–34. PDF.

  134. G. B. Shul’pin, Yu. N. Kozlov, G. V. Nizova, G. Süss-Fink, S. Stanislas, A. Kitaygorodskiy, V. S. Kulikova, «Oxidations by the reagent "O2 –H2O2– vanadium derivative –pyrazine-2-carboxylic acid" Part 12. Main features, kinetics and mechanism of  alkane hydroperoxidation», J. Chem. Soc., Perkin  Trans. 2, 2001, No. 8, 1351–1371. PDF . Electronic Supplementary Information is added. 

  135. G. Süss-Fink, L. Gonzalez, G. B. Shul’pin, «Alkane oxidation with hydrogen peroxide catalyzed homogeneously by vanadium-containing polyphosphomolybdates », Appl. Catal., A: General., 2001, 217, No. 1–2, 111–117. PDF.

  136. G. B. Shul’pin, G. Süss-Fink, A. E. Shilov, "Alkane oxygenation catalysed by gold complexes", Tetrahedron Lett., 2001, 42, 7253–7256. PDF .

  137. G. Süss-Fink, G. B. Shul’pin, “Hydrogen hydroperoxide oxidation of ethane and other alkanes  catalyzed by chromium compounds”, Petrol. Chem., 2002, 42, No. 1, 15–19. PDF.

  138. G. B. Shul’pin, G. Süss-Fink, “Hydrogen peroxide oxidation of saturated hydrocarbons  catalyzed by osmium compounds”, Petrol. Chem., 2002, 42, No. 4,  233–237. PDF.

  139. G. B. Shul’pin,  "Alkane oxygenation with hydrogen peroxide catalysed by soluble derivatives of nickel and platinum", J. Chem. Res. (S), 2002, No. 7, 351–353. PDF

  140. G. B. Shul’pin, G. V. Nizova, Yu. N. Kozlov, I. G. Pechenkina, «Oxidations by the "hydrogen peroxide–manganese(IV) complex–carboxylic acid" system. Part 4. Efficient acid-base switching between catalase and oxygenase activities of a dinuclear manganese(IV) complex in the reaction with H2O2 and an alkane», New J. Chem., 2002, 26, No. 9, 1238–1245. PDF

  141. G. V. Nizova, C. Bolm, S. Ceccarelli, C. Pavan, G. B. Shul’pin, "Hydrocarbon oxidations with hydrogen peroxide catalyzed by a soluble polymer-bound manganese(IV) complex with 1,4,7-triazacyclononane", Adv. Synth. Catal., 2002, 344, No. 8, 899–905. PDF

  142. G. V. Nizova, B. Krebs, G. Süss-Fink, S. Schindler, L. Westerheide, L. Gonzalez Cuervo, G. B. Shul’pin, "Hydroperoxidation of methane and other alkanes with H2O2 catalysed by a dinuclear iron complex and an amino acid", Tetrahedron, 2002, 58, No. 45, 9231–9237. PDF

  143. G. B. Shul’pin, E. R. Lachter, "Aerobic hydroxylation of hydrocarbons catalysed by vanadate ion",  J. Mol. Cat., A: Chem. 2003, 197, No. 1, 65–71. PDF

  144. M. H. C. de la Cruz, Yu. N. Kozlov, E. R. Lachter, G. B. Shul’pin, "Oxidations by the reagent “O2–H2O2–vanadium derivative–pyrazine-2-carboxylic acid”. Part 13. Kinetics and mechanism of the benzene hydroxylation", New J. Chem. 2003, 27, No. 3, 634–638. PDF.

  145. M. Vennat, P. Herson, J.-M. Brégeault, G. B. Shul’pin, "Vanadium-catalysed aerobic cleavage of C–C bonds in substituted cyclohexanones to afford carboxylic acids: two model complexes with tetrahedral geometry around vanadium(V)",  Eur. J. Inorg. Chem. 2003, 908–917. PDF.

  146. G. B. Shul’pin, Yu. N. Kozlov, "Kinetics and mechanism of alkane hydroperoxidation with tert-butyl hydroperoxide catalysed by a vanadate ion", Org. Biomol. Chem. 2003, 1, No. 13, 2303–2306. PDF.

  147. G. B. Shul’pin, J. Gradinaru, Yu. N. Kozlov, "Alkane hydroperoxidation with hydroperoxides catalysed by copper complexes", Org. Biomol. Chem. 2003, 1, No. 20, 3611–3617. PDF.

  148. L. Gonzalez Cuervo, Yu. N. Kozlov, G. Süss-Fink, G. B. Shul’pin, “Oxidation of saturated hydrocarbons with peroxyacetic acid catalyzed by vanadium complexes”, J. Mol. Catal. A: Chem., 2004, 218, 171–177.

  149. PDF.
  150. G. B. Shul’pin, H. Stoeckli-Evans, D. Mandelli, Yu. N. Kozlov, A. Tesouro Vallina, C. B. Woitiski, R. S. Jimenez, W. A. Carvalho, “Oxidation of alkanes with m-chloroperbenzoic acid catalyzed by iron(III) chloride and a polydentate amine”, J. Mol. Catal. A: Chem., 2004, 219, 255–264. PDF.

  151. C. B. Woitiski, Yu. N. Kozlov, D. Mandelli, G. V. Nizova, U. Schuchardt, G. B. Shul’pin, “Oxidations by the system “hydrogen peroxide–dinuclear manganese(IV) complex–carboxylic acid”. Part 5. Epoxidation of olefins including natural terpenes”, J. Mol. Catal. A: Chem., 2004, 222, 103–119. PDF.

  152. G. B. Shul’pin, G. V. Nizova, Yu. N. Kozlov, L. Gonzalez Cuervo, G. Süss-Fink, “Hydrogen peroxide oxygenation of alkanes including methane and ethane catalyzed by iron complexes in acetonitrile”, Adv. Synth. Catal., 2004, 346, No. 2–3, 317–332. PDF.

  153. G. Süss-Fink, L. Gonzalez Cuervo, B. Therrien, H. Stoeckli-Evans, G. B. Shul’pin, “Mono and oligonuclear vanadium complexes as catalysts for alkane oxidation: synthesis, molecular structure and catalytic potential”, Inorg. Chim. Acta., 2004, 357, 475–484.

  154. PDF.
  155. G.V.Nizova, Yu.N.Kozlov, G.B.Shul’pin, "Effect of acetonitrile on the catalytic decomposition of hydrogen peroxide by vanadium ions and conjugated oxidation of alkanes", Russ. Chem. Bull., 2004, No. 10, 2330–2333. PDF.

  156. Yu. N. Kozlov, G. V. Nizova, G. B. Shul’pin, “Oxidations by the reagent “O2–H2O2–vanadium derivative–pyrazine-2-carboxylic acid”. Part 14. Competitive oxidation of alkanes and acetonitrile (solvent)”, J. Mol. Catal. A: Chem., 2005, 227, No. 1–2, 247–253. PDF.

  157. G. B. Shul’pin, G. V. Nizova, Y. N. Kozlov, V. S. Arutyunov, A. C. M. dos Santos, A. C. T. Ferreira, D. Mandelli, "Oxidations by the system ‘‘hydrogen peroxide–[Mn2L2O3][PF6]2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)–oxalic acid’’. Part 6. Oxidation of methane and other alkanes and olefins in water", J. Organometal. Chem., 2005, 690, No. 20, 4498–4504. PDF.

  158. G. B. Shul’pin,  C. C. Golfeto, G. Suss-Fink, L. S. Shul’pina, D. Mandelli, "Alkane oxygenation with H2O2 catalysed by FeCl3 and 2,2’-bipyridine", Tetrahedron Lett., 2005, 46, No. 27, 4563–4567. PDF.

  159.  L. S. Shul’pina, A. R. Kudinov, G. Suss-Fink, D. A. Loginov, G. B. Shul’pin, "Oxidation of saturated hydrocarbons with peroxides catalyzed by iridium and palladium complexes", Petrol. Chem., 2005, 45, No. 5, 309–311. PDF.

  160.  M. J. D. M. Jannini, L. S. Shul’pina, U. Schuchardt, G. B. Shul’pin, "Oxidation of alkanes with hydrogen peroxide catalyzed by the "vanadate-ion–pyrazine-2-carboxylic acid" system in the presence of pyridine" (Part 15 of the series "Oxidations by the reagent O2–H2O2–vanadium derivative–pyrazine-2-carboxylic acid"),  Petrol. Chem., 2005, 45, No. 6, 413–418. PDF.

  161. G. B. Shul’pin, A. R. Kudinov, L. S. Shul’pina, E. A. Petrovskaya, "Oxidations catalyzed by osmium compounds. Part 1: Efficient alkane oxidation with peroxides catalyzed by an olefin carbonyl osmium(0) complex", J. Organometal. Chem., 2006, 691, 837–845. PDF.

  162. L. S. Shul’pina, D. Veghini, A. R. Kudinov, G. B. Shul’pin, "Oxidation of alcohols with hydrogen peroxide catalysed by soluble iron and osmium derivatives", React. Kinet. Catal. Lett., 2006,  88, No. 1,  157–164. PDF.

  163. D. Mandelli, R. A. Steffen, G. B. Shul’pin,  Carvone epoxidation by the system "Hydrogen peroxide – [Mn2L2O3][PF6]2 (L =1,4,7-trimethyl-1,4,7-triazacyclononane) –carboxylic acid": a combinatorial approach to the process optimization" <Part 7 from the series “Oxidations by the system hydrogen peroxide–[Mn2L2O3][PF6]2 (L =1,4,7-trimethyl-1,4,7-triazacyclononane)–carboxylic acid”>React. Kinet. Catal. Lett.,  2006, 88, No. 1,  165–174. PDF.

  164.  L. S. Shul’pina, A. R. Kudinov, E. A. Petrovskaya, T. V. Strelkova, G. B. Shul’pin, "Hydrogen peroxide oxidation of alkanes catalyzed by the osmium complex Os3(CO)11(eta2-PhCOCH=CHCOPh)", Petrol. Chem., 2006, 46, No. 3, 164–166. PDF.

  165. D. Veghini, L. S. Shul'pina, T. V. Strelkova, G. B. Shul’pin, "Hydrogen peroxide oxidation of 2-cyanoethanol catalyzed by metal-complexes",  Petrol. Chem. , 2006, 46, No. 3, 167–170. PDF.

  166. V. A. dos Santos , L. S. Shul’pina, D. Veghini, D. Mandelli, G. B. Shul’pin, "Highly efficient oxidation of alcohols by the system “hydrogen peroxide–[LMn(O)3MnL](PF6)2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)–oxalic acid” <Part 8 from the series “Oxidations by the system hydrogen peroxide–[Mn2L2O3][PF6]2 (L =1,4,7-trimethyl-1,4,7-triazacyclononane)–carboxylic acid”> , React. Kinet. Catal. Lett., 2006, 88, No. 2, 339–348. PDF.

  167. G. B. Shul’pin, T. Sooknoi, V. B. Romakh, G.  Süss-Fink,  L. S. Shul’pina, "Regioselective alkane oxygenation with H2O2 catalyzed by titanosilicalite TS-1", Tetrahedron Lett., 2006, 47, No. 18, 3071–3075. PDF.

  168. V. B. Romakh, B. Therrien, L. Karmazin-Brelot, G. Labat, H. Stoeckli-Evans, G. B. Shul’pin, G. Süss-Fink, "Dinuclear manganese complexes containing 1,4-dimethyl-1,4,7-triazacyclononane ligands as well as carboxylato and oxo bridges", Inorg. Chim. Acta, 2006, 359, No. 5, 1619–1626. PDF.

  169. V. B. Romakh, B. Therrien,  G. Labat, H. Stoeckli-Evans, G. B. Shul’pin, G. Süss-Fink, "Dinuclear iron, ruthenium and cobalt complexes containing 1,4-dimethyl-1,4,7-triazacyclononane ligands as well as carboxylato and oxo  or hydroxo bridges", Inorg. Chim. Acta, 2006, 359, No. 10, 3297–3305. PDF.

  170. V. B. Romakh, B. Therrien,  G. Süss-Fink, G. B. Shul’pin, "Dinuclear manganese complexes containing chiral 1,4,7-triazacyclononane-derived ligands and their catalytic potential for the oxidation of olefins, alkanes, and alcohols", Inorg. Chem., 2007, 46, No. 4, 1315–1331. PDF. Supplements: S1 (cif), S2 (doc).

  171. G. B. Shul’pin, G. S. Mishra, L. S. Shul’pina, T. V. Strelkova, A. J. L. Pombeiro, "Oxidation of hydrocarbons with hydrogen peroxide catalyzed by maltolato vanadium complexes covalently bonded to silica gel", Catal. Commun., 2007, 8, 1516–1520. PDF.

  172. V. B. Romakh, Y. N. Kozlov, G. Süss-Fink, G. B. Shul’pin, “The Kinetics and Mechanism of Oxidation of Isopropanol with the Hydrogen Peroxide–Vanadate Ion–Pyrazine-2-Carboxylic Acid System”, Russ. J. Phys. Chem. A, 2007, 81, No. 8, 1221–1229. PDF.

  173. Y. N. Kozlov, V. B. Romakh, A. Kitaygorodskiy, P. Buglyó, G. Süss-Fink, G. B. Shul’pin, “Oxidation of 2-Propanol and Cyclohexane by the Reagent “Hydrogen Peroxide-Vanadate Anion-Pyrazine-2-carboxylic Acid”: Kinetics and Mechanism”, J. Phys. Chem. A, 2007, 111, 7736–7752. PDF. Supplement: PDF.

  174. D. Mandelli, Y. N. Kozlov, C. C. Golfeto, G. B. Shul’pin, “Peroxyacetic Acid Oxidation of Olefins and Alkanes Catalyzed by a Dinuclear Manganese(IV) Complex with 1,4,7-trimethyl-1,4,7-triazacyclononane”, Catal. Lett., 2007, 118, 22–29. PDF.

  175. G. V. Nizova, G. B. Shul’pin, “A unique rate-accelerating effect of certain amino acids in the H2O2 oxidation of alkanes catalyzed by a dinuclear manganese complex containing 1,4,7-trimethyl-1,4,7-triazacyclononane”<Part 9 from the series “Oxidations by the system ‘hydrogen peroxide–[Mn2L2O3][PF6]2 (L =1,4,7-trimethyl-1,4,7-triazacyclononane)–carboxylic acid’”>", Tetrahedron, 2007, 63, No. 33, 7997–8001. PDF.

  176. G. B. Shul’pin, M. G. Matthes, V. B. Romakh, M. I. F. Barbosa, J. L. T. Aoyagi, D. Mandelli, “Oxidations by the system ‘hydrogen peroxide–[Mn2L2O3][PF6]2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)–carboxylic acid’. Part 10. Co-catalytic effect of different carboxylic acids in the oxidation of cyclohexane, cyclohexanol and acetone”, Tetrahedron, 2008, 64, No. 8, 2143–2152. PDF. Supplement: PDF.

  177. Y. N. Kozlov, G. V. Nizova, G. B. Shul’pin, “Alkane oxidation by the system ‘tert-butyl hydroperoxide–[Mn2L2O3][PF6]2 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)– carboxylic acid’”, J. Phys. Org. Chem., 2008, 21, No. 2, 119–126. PDF.

  178. G. B. Shul’pin, T. Sooknoi, L. S. Shulpina, “The Influence of Organic Additives on the Regioselectivity of Oxygenation of Alkanes with Hydrogen Peroxide in the Presence of TS-1 Titanium Silicalite”, Petrol. Chem., 2008, 48, No. 1, 36–39. PDF.

  179. L. S. Shul'pina, K. Takaki, T. V. Strelkova, G. B. Shul’pin, Petrol. Chem., 2008, 48, in press.

  180.  V. B. Romakh, G. Süss-Fink, G. B. Shul’pin, Petrol. Chem., 2008, 48, in press.

  181. G. B. Shul’pin, M. V. Kirillova,  T. Sooknoi, A. J. L. Pombeiro, “Oxidation of Saturated Hydrocarbons to Alkyl hydroperoxides by a ‘H2O2/Titanosilicalite-1/NaOH/MeCN’ system”, Catal. Lett., 2008, in press.

PATENTS:

  1. A. N. Nesmeyanov, M. I. Rybinskaya, G. B. Shul’pin, “Method for isolating organometallic compounds and thiourea adducts with organometallic compounds”, Pat. USA 3,950,373, 1976. PDF .

  2. A. N. Nesmeyanov, M. I. Rybinskaya, G. B. Shul’pin, “Adducts of organometallic compounds with thiourea”, Pat. UK 1457605, 1976. PDF.

  3. A. Hoehn, G. Suess-Fink, G. B. Shulpin, G. V. Nizova, "Oxidation of methane and ethane to products containing carbon, hydrogen and oxygen in the presence of metal complexes", Ger. Offen. DE 19,720,344, 1997 (to BASF A.–G.), (Chem. Abstr. 128:48802p, 1998.  PDF. ChemFinder

  4.  G. Süss-Fink, G. B. Shul’pin, L. S. Shul’pina, "Process for the production of ketones", Pat. USA 7,015,358 (March 21, 2006; Filled 2002, to Lonza A.–G., Switzerland). Eur. Pat. EP 1 385 812 A0 (Application: WO 02/088063, art. 158 of the EPC). PDFChemFinder

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