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Books
1.
S. P. Gubin, G. B. Shul’pin,
The Chemistry of Complexes with Metal-Carbon Bonds,
Novosibirsk, Nauka, 1984, 280 pp. (in
Russian).
2.
G. B. Shul’pin,
Organic Reactions Catalyzed by Metal Complexes, Moscow, Nauka,
1988, 285 pp. (in
Russian).
3.
A. E. Shilov, G. B. Shul’pin,
Activation and Catalytic Reactions of Hydrocarbons, Moscow,
Nauka, 1995, 400 pp. (in
Russian).
4.
A. E. Shilov, G. B. Shul’pin, “Activation and Catalytic
Reactions of Saturated Hydrocarbons in the Presence of Metal
Complexes”, Kluwer Academic Publishers, Dordrecht/Boston/London,
2000, (548 pp.)
5.
G.
B. Shul’pin, "Oxidations of C–H Compounds
Catalyzed by Metal Complexes", in M. Beller, C. Bolm (Eds.), Transition Metals for Organic
Synthesis, Wiley–VCH, Weinheim/New York, vol. 2 (chapter 2.2),
2nd edition, 2004, pp. 215–242.
6.
G. B. Shul’pin, Chapter
“Selectivity in C–H functionalizations”, in: “Comprehensive
Inorganic Chemistry II”, Vol. 6, Eds. J. Reedijk, K.
Poeppelmeier, L. Casella, Elsevier, in press.
7.
G. B. Shul’pin, “Engrossing
Chemistry”, Moscow, Khimiya, 1984, 184 pp, second edition:
Moscow, URSS, 2011, in Russian.
8.
G. B. Shul’pin, “The World of
Unusual Molecules: Organometallic Complexes”, Moscow, Nauka,
1986, 176 pp, in Russian.
9.
G. B. Shul’pin, “Chemistry for
Everyone”, Moscow, Znanie, 1987, 144 pp, in Russian.
10.
G. B. Shul’pin, “Engrossing
Chemistry”, Sofia, Narodna Prosveta, 1988, 168 pp, in Bulgarian.
11.
C. Shulpin, “Que es la quimica
organica”, Ediciones Quinto Sol, Mexico, 1988, 272 pp., in
Spanish.
12.
G. B. Shul’pin, “Learning About
Chemistry”, Moscow, Mir Publishers, 1989, 232 pp., in English.
13.
G. B. Sulpin, “Okouzlujici
chemie”, Polytechnicka kniznice SNTL, Praha 1989, 158 pp. in
Czech.
14.
G. B. Shulpin, “Quimica para todos”, Moscu, Editorial
Mir, 1990, 264 pp.
Reviews
15.
G. B. Shul’pin, M. I. Rybinskaya, “Ferocenophanes”, Russ.
Chem. Rev., 1974, 43, No. 9, 716–732.
16.
G. B. Shul’pin, “Diastereotopy in
Transition Metal Complexes”, Russ.
Chem. Rev., 1980,
49, No. 7, 645–654.
17.
A. E. Shilov, G. B. Shul’pin,
“Activation and catalytic reactions of alkanes in solutions of metal
complexes”, Russ. Chem. Rev.,
1987, 56, No. 5, 442–464.
18.
A. E. Shilov, G. B. Shul’pin,
“Activation of the C–H bond by metal complexes”, Russ.
Chem. Rev.,
1990, 59, No. 9, 853–867.
19.
A. E. Shilov, G. B. Shul’pin,
“Activation of C–H Bonds by Metal Complexes”, Chem.
Rev., 1997,
97, No. 8, 2879–2932.
20.
G. B. Shul’pin, "Metal-catalysed
hydrocarbon oxygenations in solutions: the dramatic role of
additives: a review", J. Mol.
Catal., A: Chem., 2002, 189,
No. 1, 39–66.
21.
G. B. Shul’pin, "Metal-catalysed hydrocarbon oxidations",
Comptes Rendus, Chimie, 2003, 6, 163–178.
22.
G. B. Shul’pin, “Hydrocarbon Oxygenations with Peroxides
Catalyzed by Metal Compounds”, Mini-Rev. Org. Chem., 2009,
6, 95–104.
23.
G.
B. Shul’pin, “Selectivity enhancement in
functionalization of C–H bonds: A review”, Org. Biomol. Chem.,
2010, 8, No. 19, 4217–4228.
Original Papers
24.
A. N. Nesmeyanov, M. I. Rybinskaya, N. S. Kochetkova, V. N.
Babin, G. B. Shul’pin, «Synthesis of complexes of iron with
nitrogen-containing heterocyclic ligands 4-acyltriazoles and
3,5-dimethylpyrazole», Doklady Chemistry, 1968, 181,
Nos. 4–6, 767–769.
25.
A. N. Nesmeyanov, M. I. Rybinskaya, G. B. Shul’pin,
“Cyanoethylation of ferrocene”, Syn. Inorg. Metal-org. Chem.,
1971, 1, No. 4, 279–285.
26.
M. I. Rybinskaya, G. B. Shul’pin, L. M. Korneva, A. A.
Pogrebnyak, «Cyanoethylation of cyclopentadienide anion and
synthesis of beta-cyanoethylferrocene», Bull. Acad. Sci. USSR,
Div. Chem. Sci., 1972, 21, No. 9, 2001–2004.
27.
A. N. Nesmeyanov, M. I. Rybinskaya, G. B. Shul’pin, A. A.
Pogrebnyak, «Synthesis of ferrocenophanes by the cyclization of
dinitriles», Doklady Chemistry, 1973, 212, Nos. 1–3,
709–711.
28.
G. B. Shul’pin, A. A. Koridze, A. A. Pogrebnyak, M. I.
Rybinskaya, A. N. Nesmeyanov, “Synthesis of
1,1'-bis(beta-cyanovinyl) and 1,1'-bis(beta-cyanoethyl)ferrocenes”,
Syn. Inorg. Metal-org. Chem., 1973, 3, No. 1,
83–92.
29.
A. N. Nesmeyanov, G. B. Shul’pin, L. A. Fedorov, P. V.
Petrovsky, M. I. Rybinskaya, “13C and 1H NMR
spectra of monosubstituted ferrocenes containing a chiral centre in
the substituent”, J. Organometal. Chem., 1974, 69,
429–435.
30.
A. N. Nesmeyanov, G. B. Shul’pin, M. I. Rybinskaya, P. V.
Petrovskii, «C13 Nuclear magnetic resonance spectra of
acylferrocenes in protonic acids», Doklady Chemistry, 1974,
215, Nos. 1–3, 188–191.
31.
A. N. Nesmeyanov, G. B. Shul’pin, P. V. Petrovskii, V. I.
Robas, M. I. Rybinskaya, «13C and 1H Nuclear
magnetic resonance spectra of [5]ferrocenophanes», Doklady
Chemistry, 1974, 215, Nos. 1–3, 211–215.
32.
A. N. Nesmeyanov, G. B. Shul’pin, L. M. Korneva, M. I.
Rybinskaya, «Coordination of the cyclopentadienyldicarbonylmanganese
group with the double bond of vinylferrocenes», Doklady Chemistry,
1974, 217, Nos. 4–5, 562–565.
33.
A. N. Nesmeyanov, G. B. Shul’pin, L. V. Rybin, N. T. Gubenko,
M. I. Rybinskaya, P. V. Petrovskii, V. I. Robas, «Iron carbonyl
complexes of ferrocene analogs of chalcone», J. Gen. Chem. USSR,
1974, 44, No. 9, Part 2, 1994–2001.
34.
A. N. Nesmeyanov, G. B. Shul’pin, M. I. Rybinskaya,
«Investigation of ferrocenophanes by 13C and 1H
nuclear magnetic resonance», Doklady Chemistry, 1974, 218,
Nos. 1–3, 705–707.
35.
A. N. Nesmeyanov, G. B. Shul’pin, M. I. Rybinskaya, «Ionic
hydrogenation of keto, alcohol, and vinyl groupings in disubstituted
heteroannular ferrocenes», Bull. Acad. Sci. USSR, Div. Chem. Sci.,
1975, 24, No. 12, 2714–2716.
36.
A. N. Nesmeyanov, G. B. Shul’pin,
M. I. Rybinskaya, «Separation of metallocenes by means of inclusion
compounds with thiourea», Doklady Chemistry, 1975, 221,
Nos. 1–3, 229–231.
37.
A. N. Nesmeyanov, M. I. Rybinskaya,
G. B. Shul’pin, A. A. Pogrebnyak, “Synthesis of ferrocenophanes by
cyclization of dinitriles”, J. Organometal.
Chem., 1975, 92,
341–367.
38.
A. N. Nesmeyanov, G. B. Shul’pin, D. V. Zagorevskii, M. I.
Rybinskaya, «Synthesis of [5]ruthenocenophan derivatives»,
Doklady Chemistry, 1976, 229, Nos. 4–6, 523–525.
39.
A. N. Nesmeyanov, M. I. Rybinskaya, G. B. Shul’pin, M. V.
Tolstaya, «Synthesis of a doubly bridged five-membered ferrocenophan»,
Doklady Chemistry, 1976, 229, Nos. 4–6, 540–543.
40.
A. N. Nesmeyanov, G. B. Shul’pin, V. V. Krivykh, M. I.
Rybinskaya, «Reduction of the double bond with molybdenum carbonyl»,
Doklady Chemistry, 1977, 232, Nos. 1–3, 26–27.
41.
A. N. Nesmeyanov, G. B. Shul’pin, M. V. Tolstaya, M. I.
Rybinskaya, «Reduction of alpha-oxo and alpha-hydroxy derivatives of
ferrocenophanes by sodium borohydride in the presence of a Lewis
acid (aluminum chloride or boron trifluoride)», Doklady Chemistry,
1977, 232, Nos. 4–6, 96–98.
42.
A. N. Nesmeyanov, M. V. Tolstaya, M. I. Rybinskaya, G. B.
Shul’pin, N. G. Bokii, A. S. Batsanov, Y. T. Struchkov, “Synthesis
and structure of the 1,1’-trimethylene-benzenecyclopentadienyliron
cation” J. Organometal. Chem., 1977, 142, 89–93.
43.
G. B. Shul’pin, L. P. Rozenberg, R.
P. Shibaeva, A. E. Shilov, «Synthesis and structure of the sigma-naphthyl
derivative of platinum(IV) formed by the reaction of naphthalene
with H2PtCl6)», Kinetics and Catalysis,
1979, 20, No. 6, Part. 2, 1296-1298.
44.
G. B. Shul’pin, A. E. Shilov, A. N.
Kitaigorodskii, J. V. Zeile Krevor, “The reaction of H2PtCl6
with aromatic compounds affording the sigma-aryl complexes of
Pt(IV). II. The synthesis of Pt(IV) complexes of benzene,
alkylbenzenes and chlorinated benzenes”, J. Organometal.
Chem.,
1980, 201, 319–325.
45.
G. B. Shul’pin, “The reaction of H2PtCl6
with aromatic compounds affording the sigma-aryl complexes of
Pt(IV). III. The synthesis of Pt(IV) complexes of benzenes
containing electron-withdrawing substituents”, J. Organometal.
Chem.,
1981, 212, 267–274.
46.
G. B. Shul’pin, A. N. Kitaigorodskii, “The reaction of H2PtCl6
with aromatic compounds affording the sigma-aryl complexes of
Pt(IV). IV. The synthesis of Pt(IV) complexes of fluorinated
benzenes and the electronic influence of the platinum moiety”, J.
Organometal. Chem., 1981, 212, 275–281.
47.
R. P. Shibaeva, L. P. Rozenberg, R. M. Lobkovskaya, A. E.
Shilov, G. B. Shul’pin, “The crystal and molecular structures of
Pt(IV) complexes of naphthalene and o-nitrotoluene <Part V
from the series “The reaction of H2PtCl6 with
aromatic compounds affording the sigma-aryl complexes of Pt(IV)””,
J. Organometal. Chem., 1981, 220, 271–276.
48.
G. B. Shul’pin, «Reaction of
aromatic compounds with H2PtCl6 in CF3COOH–H2O
system leading to the preparation of anionic sigma-aryl complexes of
Pt(IV)», J. Gen. Chem. USSR,
1981, 51, No. 9, Part 2, 1808–1818.
49.
G. B. Shul’pin, “Reduction of
carbonyl group to methylene group in ferrocene and ruthenocene
derivatives by sodium borohydride in the presence of protonic and
Lewis acids”, J. Gen. Chem. USSR,
1981, 51, No. 9, Part 2, 1854.
50.
G. B. Shul’pin, «The formation of
sigma-aryl complexes of platinum(IV) in the reaction of
chloroplatinic acid with aromatic compounds», Kinetics and
Catalysis, 1981, 22, No. 2, Part 2, 397–398.
51.
G. B. Shul’pin, G. V. Nizova,
«Formation of sigma-aryl complexes of platinum(II) in the reaction
of aromatic compounds with salts of Pt(II) and their oxidation under
the action of H2PtCl6», Kinetics and
Catalysis, 1981, 22, No. 4, Part 2, 834–836.
52.
G. B. Shul’pin, A. N.
Kitaigorodskii, «The relative rates of the formation of sigma-aryl
derivatives of platinum(IV) in the reaction of aromatic compounds
with chloroplatinic acid», Russ. J. Phys.
Chem., 1981, 55,
No. 1, 150–151.
53.
G. B. Shul’pin, A. T. Nikitaev,
“Formation rates of anionic sigma-tolyl complex of platinum(IV) in
reaction of H2PtCl6 with toluene and para-meta
isomerization of this complex in CF3COOH ”,
Bull. Acad. Sci. USSR, Div. Chem.
Sci., 1981, 30, No. 6, Part 2,
1138–1140.
54.
G. V. Nizova, G. B. Shul’pin,
“Arylation of olefins by phenyl derivatives of nontransition metals
in presence of platinum(IV) and gold(III) complexes ”, Bull.
Acad. Sci. USSR, Div. Chem. Sci.,
1981, 30, No. 11, Part 2, 2211.
55.
G. B. Shul’pin, P. Lederer, G. V.
Nizova, “Formation of sigma-aryl complexes of platinum(IV) in the
reactions of H2PtCl6 with phenylboronic acid
and with the tetraphenylborate ion. Arylation of olefins with phenyl
derivatives of boron”, J. Gen. Chem USSR, 1982, 52,
No. 6, Part 2, 1262.
56.
G. V. Nizova, J. V. Z. Krevor, A.
N. Kitaigorodskii, G. B. Shul’pin, “Isolation of platinum(II)
pi-olefin complexes formed by the reaction of saturated hydrocarbons
with H2PtCl6 in CF3COOH-H2O
solution”, Bull. Acad. Sci.
USSR, Div. Chem. Sci., 1982, 31,
No. 12, Part 2, 2480–2482.
57.
G. V. Nizova, G. B. Shul’pin,
“Interaction of HAuCl4 with aromatic compounds in protic
media. Formation of sigma-aryl complexes of gold”, React. Kinet.
Catal. Lett.,
1982, 20, No. 1-2, 69–71.
58.
G. B. Shul’pin, G. V. Nizova, A. E.
Shilov, “Photoinduced reactions of PtCl62–
with saturated hydrocarbons and other C–H containing compounds”
J. Chem. Soc., Chem. Commun.,
1983, 671–672.
59.
G. B. Shul’pin, G. V. Nizova,
“Synthesis of Pt(II) pi-olefin complexes by reaction of Na2PtCl6
or Na2PtCl4 in acetone using light
irradiation”, Bull. Acad. Sci.
USSR, Div. Chem. Sci., 1983, 32,
No. 3, Part 2, 607–608.
60.
G. V. Nizova, P. Lederer, G. B.
Shul’pin, “Oxidative coupling of arenes or aryl derivatives with
olefins under the action of Pt(IV) compounds” Oxid.
Commun., 1983,
4, Nos. 1–4, 131–135.
61.
В.В.Замащиков,
Е.С.Рудаков,
С.А.Митченко,
А.Н.Китайгородский,
Г.Б.Шульпин,
“Утворення етильного комплексу Pt(IV)
в системi CH3CH2I–PtCl42–-–D2O
i його реакцii”, Допов.
АН Укр. РСР, Сер. Б, 1983, № 6, 33-35. (in
Ukrainian).
62.
N. Zilkova, G. B. Shul’pin, P.
Lederer, “Photochemical oxidation of ethylbenzene and other
hydrocarbons in the presence of Co(III) 2,4-pentadionate”, Coll.
Czech. Chem. Commun.,
1984, 49, 2376–2381.
63.
M. V. Serdobov, G. V. Nizova, G. B.
Shul’pin, “Formation of organometallic complexes of Pt(II) and Pt(IV)
in reactions of PtCl62– with alkanes, olefins
and aromatics induced by gamma-irradiation” J. Organometal.
Chem.,
1984, 265, C12–C14.
64.
V. V. Zamaschchikov, E. S. Rudakov, S. A. Mitchenko, G. V.
Nizova, A. N. Kitaigorodskii, G. B. Shul’pin, “Formation of the
sigma-acetonyl Pt(IV) complex in the reaction of iodoacetone with
PtCl42– in aqueous solution”, Bull. Acad.
Sci. USSR, Div. Chem. Sci., 1984, 33, No. 7, Part 2,
1520–1522.
65.
G. B. Shul’pin, G. V. Nizova, A. E. Shilov, A. T. Nikitaev,
M. V. Serdobov, “Photoinduced reactions of organic compounds with
transition metal complexes. Communication
1. First example of substitution in the aromatic nucleus in
photoexcitation of an electrophilic reagent: formation of sigma-aryl
complexes of Pt(IV) in the reaction of PtCl62–
with arenes”, Bull. Acad. Sci.
USSR, Div. Chem. Sci., 1984, 33,
No. 12, Part 1, 2454–2459.
66.
G. V. Nizova, M. V. Serdobov, A. T. Nikitaev, G. B. Shul’pin,
“Photoinduced reactions of organic compounds with transition metal
complexes. II. Reaction of PtCl62–
with acetone to give a sigma-acetonyl complex of Pt(IV). Detection
of Pt(III) compounds by ESR”, J. Organometal. Chem., 1984,
275, 139–144.
67.
G. B. Shul’pin, G. V. Nizova, A. N.
Kitaigorodskii, M. V. Serdobov, “Photoinduced reactions of organic
compounds with transition metal complexes. III. Formation of a
sigma-methyl complex of Pt(IV) and a pi-ethylene complex of Pt(II)
in photochemical and thermal reactions of PtCl62–-
with methyl and ethyl derivatives of tin or germanium. Thermal
oxidative addition of Me4Sn to PtCl42–
to afford the sigma-methyl complex of Pt(IV)”, J. Organometal.
Chem.,
1984, 275, 273–282.
68.
G. B. Shul’pin, G. V. Nizova, P. Lederer, “Photoinduced
reactions of organic compounds with transition metal complexes. IV.
Thermal and photochemical reactions of PtCl62–
and PtCl42– with olefins and alcohols:
convenient synthesis of pi-olefin complexes of Pt(II)”, J.
Organometal. Chem., 1984, 275, 283–294.
69.
A. N. Kitaigorodskii, V. M.
Nekipelov, A. T. Nikitaev, G. B. Shul’pin, “The reaction of PtCl62–
with aromatic compounds to afford anionic sigma-aryl complexes of
Pt(IV). VI. The 195Pt and 13C NMR spectra of
sigma-aryl complexes”, J. Organometal.
Chem., 1984, 275,
295–301.
70.
G. B. Shul’pin, G. V. Nizova, “The
reaction of PtCl62– with aromatic compounds to
afford anionic sigma-aryl complexes of Pt(IV). VII. Cleavage of
aryl-element bonds (element = Hg, Sn, Pb or B). Arylation reactions
of arenes and olefins with aryl complexes of Pt(IV)”, J.
Organometal. Chem.,
1984, 276, 109–114.
71.
G. B. Shul’pin, G. V. Nizova, A. T. Nikitaev, “The reaction
of PtCl62– with aromatic compounds to afford
anionic sigma-aryl complexes of Pt(IV). VIII. Kinetics and
mechanisms of thermal, photochemical and gamma-induced reactions
with arenes and arylmercury compounds (electrophilic substitution
involving electron transfer)”, J. Organometal. Chem.,
1984, 276, 115–153.
72.
A. T.
Nikitaev, G. V. Nizova, V. V. Lontsov, G. B. Shul’pin, “The kinetics
and mechanism of formation and para-meta isomerization of the sigma-tolyl
complex of platinum(IV) in acidic media”, J. Org. Chem. USSR,
1984, 20, No. 12, Part 2, 2339–2343.
73.
G. B. Shul’pin, G. V. Nizova, A. T.
Nikitaev, “Photoinduced reactions of organic compounds with
complexes of transition metals. V. Formation of a pi-olefin complex
of Pt(II) in the reaction of hexane with PtCl62–
in CH3COOH under the action of light”, J. Gen. Chem.
USSR,
1985, 55, No. 6, Part 2, 1251–1256.
74.
G. B. Shul’pin, P. Lederer, G. V. Nizova, M. V. Serdobov,
“Photoinduced reactions of organic compounds with complexes of
transition metals. VI. Reduction of the PtCl62–
ion with carbon monoxide under the action of light”, J. Gen.
Chem. USSR, 1986, 56, No. 11, Part 2, 2316–2317.
75.
V. V. Zamashchikov, E. S. Rudakov, S. A. Mitchenko, G. V.
Nizova, A. N. Kitaigorodskii, G. B. Shul’pin, “Intermediate
formation of an ethyl complex of platinum in the system EtI – PtCl42–
– H2O”, Bull. Acad. Sci. USSR. Div. Chem. Sci.,
1986, 35, No. 1, Part 2, 175–178.
76.
G. V. Nizova, G. B. Shul’pin,
“Reaction of sterically hindered arylmercury compounds with Pt(IV),
Pt(II), and Pd(II) chloride complexes”, Bull.
Acad. Sci. USSR. Div. Chem. Sci.,
1986, 35, No. 10, Part 2, 2174–2176.
77.
G. B. Shul’pin, G.V.Nizova,
“Reduction of tolan to stilbene by sodium borohydride catalyzed by
rhodium complexes”, Bull. Acad.
Sci. USSR. Div. Chem. Sci., 1986,
35, No. 10, Part 2, 2176–2177.
78.
G. B. Shul’pin, A. E. Shilov, G. V. Nizova, A. K.
Yatsimirskii, S. A. Deiko, P. Lederer, “Isomeric composition of
ditolyls formed upon the thermal decomposition of an anionic Pt(IV)
sigma-tolyl chloride complex”, Bull. Acad. Sci. USSR, Div. Chem.
Sci.,1986, 35, No. 10, Part 2, 2177–2179.
79.
G. B. Shul’pin, P. Lederer, E. Macova, “Photooxidation of
hydrocarbons by chromium(VI) oxo compounds”, Bull. Acad. Sci.
USSR, Div. Chem. Sci., 1986, 35, No. 11, Part 2,
2422.
80.
G. V. Nizova, G. B. Shul’pin, “Oxidation of mesitylene by
PtCl62– ions in trifluoroacetic acid”,
Bull. Acad. Sci. USSR, Div. Chem. Sci., 1987, 36, No. 4,
Part 2, 862–863.
81.
G. V. Nizova, G. B. Shul’pin,
“Reactions of 2,4-dimethylphenylmercury and pentamethylphenylmercury
acetates with olefins in the presence of Pd(II) and Pt(IV)
complexes”, Bull. Acad. Sci.
USSR, Div. Chem. Sci., 1987,
36, No. 9, Part 2, 1920–1921.
82.
G. B. Shul’pin, G. V. Nizova, M. V.
Serdobov, “Photoinduced reactions of organic compounds with
complexes of transition metals. VII. Photochemical oxidative
coupling of arenes under the action of chloride complexes of Os(IV),
Ir(IV), and Rh(III)”, J. Gen. Chem.
USSR, 1987, 57,
No. 2, Part 2, 402–404.
83.
G. B. Shul’pin, P. Lederer, Y. V.
Geletii, “Photoinduced reactions of organic compounds with complexes
of transition metals. VIII. Photochemical chlorination of saturated
and aromatic hydrocarbons with AuCl4–complex”,
J. Gen. Chem. USSR,
1987, 57, No. 3, Part 2, 543–548.
84.
G. B. Shul’pin, G. V. Nizova, Y. V. Geletii, “Photoinduced
reactions of organic compounds with complexes of transition metals.
IX. Oxidation of hexane and other alkanes and isomerization of
2-hexene under the influence of the PtCl62–
ion in CF3COOH”, J. Gen. Chem. USSR, 1987, 57,
No. 3, Part 2, 548–552.
85.
G. B. Shul’pin, M. M. Kats, G. V. Nizova, “Photooxidation of
alkylbenzenes and cyclohexane by atmospheric oxygen in acetonitrile
sensitized by o-phenanthroline”, Bull. Acad. Sci. USSR,
Div. Chem. Sci., 1988, 37, No. 11, Part 2, 2395.
86.
G. B. Shul’pin, M. M. Kats, Y. N. Kozlov, “Oxidation of
benzene and alkylbenzenes by xenone trioxide catalyzed by Cr(VI) oxo
compounds or Mn and Fe porphyrin complexes”, Bull. Acad. Sci.
USSR, Div. Chem. Sci., 1988, 37, No. 11, Part 2,
2396.
87.
G. B. Shul’pin, A. N. Druzhinina, “Oxidation of ethylbenzene
by atmospheric oxygen and iodosobenzene catalyzed by CrO3”,
Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989, 37, No.
5, Part 2, 1079–1081.
88.
G. B. Shul’pin, M. M. Kats, “Photocatalytic oxidation of
cyclohexane by atmospheric oxygen in CH2Cl2 in
the presence of an oxometallate-tetraalkylammonium system”, Bull.
Acad. Sci. USSR, Div. Chem. Sci., 1989, 38, No. 10, Part
2, 2202.
89.
G. V. Nizova, G. B. Shul’pin,
“Oxidation of alkanes by atmospheric oxygen in CH3CN or
CH2Cl2 catalyzed by AuCl4–
ions upon light irradiation”, Bull.
Acad. Sci. USSR, Div. Chem. Sci.,
1989, 38, No. 10, Part 2, 2205.
90.
Г.Б.Шульпин,
С.Ю.Скрипник,
С.А.Дейко,
А.К.Яцимирский,
“Распад sigma-арильных комплексов
Pt(IV) – промежуточных соединений в окислении аренов ионом
PtCl62-”, Металлоорган.
химия, 1989, 2, № 6, 1301-1304. (in
Russian).
91.
G. B. Shul’pin, A. N. Druzhinina, M. M. Kats, "Oxidation of
hydrocarbons by iodobenzene, catalysed by oxocompounds of chromium
and vanadium", Petroleum Chemistry U.S.S.R., 1989, 29,
No. 3, 251 (Abstract).
92.
G. B. Shul’pin, E. Macova, P.
Lederer, “Photoinduced reactions of organic compounds with
transition-metal complexes. X. Oxidation of alkanes and alkyl
benzenes by Cr(VI) oxo compounds on exposure to light”, J. Gen.
Chem. USSR,
1989, 59, No. 11, Part 2, 2329–2334.
93.
G. B. Shul’pin, A. N.
Kitaigorodskii, “Photoinduced reactions of organic compounds with
transition-metal complexes. XI. Relative rates of oxidation of the
methyl group in substituted toluenes by Cr(VI) oxo compounds in
thermal and photochemical reactions”, J. Gen. Chem.
USSR, 1989,
59, No. 11, Part 2, 2335–2337.
94.
G. B. Shul’pin, M. M. Kats,
“Photoinduced reactions of organic compounds with transition-metal
complexes. XII. Oxidation of toluene to benzaldehyde by oxygen in
the presence of the Cr(VI) – (C4H9)4N+
system”, J. Gen. Chem. USSR,
1989, 59, No. 11, Part 2, 2338–2340.
95.
G. B. Shul’pin, M. M. Kats,
“Photoinduced reactions of organic compounds with transition-metal
complexes. XIII. Oxidation of alkylbenzenes with oxygen catalyzed by
polyoxometalate ions”, J. Gen. Chem.
USSR, 1989, 59,
No. 12, Part 2, 2447–2450.
96.
G. B. Shul’pin, M. M. Kats, P. Lederer, “Photoinduced
reactions of organic compounds with transition-metal complexes. XIV.
Photooxidation of toluene to benzaldehyde with oxygen in CH3COOH
catalyzed by FeCl3 and phenanthroline”, J. Gen. Chem.
USSR, 1989, 59, No. 12, Part 2, 2450–2455.
97.
Г.И.Низова, Г.Б.Шульпин, “Образование sigma-арильных комплексов Pt(IV)
в фотохимической реакции иона PtCl62– с
аренами в CH2Cl2 (фотоэлектрофильное
замещение)”, Металлоорган. химия, 1990, 3, № 2, 463-464.
(in Russian).
98.
A. N.
Druzhinina, G.
V. Nizova,
G. B.
Shul’pin, “Hydrogen
peroxide oxidation of hydrocarbons catalyzed by Cr(VI)
oxo compounds”, Bull.
Acad. Sci. USSR, Div. Chem. Sci.,
1990, 39, No. 1, Part 2, 194–195.
99.
G. B. Shul’pin, A. N. Druzhinina, G. V. Nizova,
“Photooxidation of cyclohexane by (Bu4N)2Cr4O13
in acetonitrile or CH2Cl2”, Bull.
Acad. Sci. USSR, Div. Chem. Sci., 1990, 39, No. 1, Part
2, 195–196.
100.
G. V. Nizova, M. M. Kats, G. B. Shul’pin, “Photooxidation of
alkanes by oxygen catalyzed by CuCl2 in acetonitrile”,
Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990, 39,
No. 3, Part 2, 618–619.
101.
M. M. Kats, G. B. Shul’pin, “Photooxidation of alkanes and
benzene by polyvanadate in CF3COOH”, Bull. Acad. Sci.
USSR, Div. Chem. Sci., 1990, 39, No. 10, Part 2,
2233.
102.
G. B. Shul’pin, A. N.
Kitaigorodskii, “Oxidation of substituted toluenes by oxygen in the
presence of Fe or Cu powder”, J. Gen. Chem.
USSR, 1990, 60,
No. 5, Part 1, 920–921.
103.
G. B. Shul’pin, M. M. Kats, “Ferric
chloride catalyzed photooxidation of alkanes by air in organic
solvents”, React. Kinet. Catal.
Lett., 1990, 41, No. 2,
239–243.
104.
G. B. Shul’pin, G. V. Nizova,
“Photoinduced reactions of organic compounds with transition-metal
complexes. XV. Photooxidation of alkylaromatic and saturated
hydrocarbons by air in CH3COOH in the presence of AuCl4–
or PtCl62–”, J. Gen. Chem.
USSR, 1990, 60,
No. 9, Part 2, 1892–1894.
105.
G. V. Nizova, G. B. Shul’pin,
“Photoinduced reactions of organic compounds with transition-metal
complexes. XVI. Air oxidation of alkylaromatic and saturated
hydrocarbons sensitized by UO22+”, J. Gen.
Chem. USSR,
1990, 60, No. 9, Part 2, 1895–1896.
106.
G. B. Shul’pin, G. V. Nizova, M. M.
Kats, “Photoinduced reactions of organic compounds with
transition-metal complexes. XVII. Oxidation of saturated and
arylalkane hydrocarbons with atmospheric oxygen photosensitized with
metal chlorides”, J. Gen. Chem.
USSR, 1990, 60, No. 12, Part 2,
2447–2449.
107.
G. B. Shul’pin, M. M. Kats,
“Photoinduced reactions of organic compounds with transition-metal
complexes. XVIII. Oxidation of saturated and alkylaromatic compounds
by CrO3 in acetonitrile on irradiation”, J. Gen. Chem.
USSR,
1991, 61, No. 3, Part 2, 684–685.
108.
G. B. Shul’pin, M. M. Kats,
“Photochemical oxidation of saturated and alkylaromatic hydrocarbons
by atmospheric oxygen in CH3CN or CH2Cl2
solution, catalysed by iron(III) halides <Report XX from series
“Photoinitiated reactions of organic compounds with metal
complexes””, Petrol.Chem. 1991, 31, No. 5, 647–656.
109.
G. B. Shul’pin, G. V. Nizova, M. M.
Kats, “Oxidation of alkanes and arylalkanes in solutions by
atmospheric oxygen during light irradiation, catalysed by copper
halides <Report XXI from series “Photoinitiated reactions of organic
compounds with metal complexes”” Petrol.
Chem. 1991, 31,
No. 5, 657–665.
110.
G. B. Shul’pin, A. N. Druzhinina, G. V. Nizova, “Photoinduced
reactions of organic compounds with transition metals. 22.
Polychromate-catalyzed photooxygenation of alkanes and other
compounds by O2 or air in CH2Cl2”
Bull. Acad. Sci. USSR, Div. Chem. Sci., 1991, 40,
No. 11, Part 1, 2145–2149.
111.
G. V. Nizova, G. B. Shul’pin, “Photooxygenation of saturated
and alkylaromatic hydrocarbons, catalysed by platinum metal halides
<Report XXIII from series “Photoinitiated reactions of organic
compounds with transition metal complexes””, Petrol.Chem.,
1991, 31, No. 6, 829–835.
112.
J. Muzart, A. N’ait Ajjou, G. V. Nizova, G. B. Shul’pin,
“Hydrogen peroxide oxidation of cyclohexane, indane, and styrene in
the presence of CrO3 or (Bu3SnO)2CrO2”,
Bull. Acad. Sci. USSR, Div. Chem. Sci., 1991, 40,
No. 6, Part 2, 1294-.
113.
A. N.
Druzhinina, L. S. Shul’pina, G. B. Shul’pin, “Photochemical
oxidation of hydrocarbons by atmospheric oxygen in acetonitrile
catalyzed by cyclopentadienyliron complexes”, Bull. Acad. Sci.
USSR, Div. Chem. Sci., 1991, 40, No. 7, Part 2,
1492–1494.
114.
G. B. Shul’pin, S. A. Deiko, A. K. Yatsimirskii, “Oxidation
of toluene by the PtBr62– ion in CF3COOH–H2O
solution”, J. Gen. Chem. USSR, 1991, 61, No. 4, Part
1, 742–744.
115.
A. N. Druzhinina, G. B. Shul’pin,
“Biomimetic activation of the C–H bond. 1. Oxygenation of
hydrocarbons by atmospheric oxygen in the presence of metal
chlorides and ascorbic acid or glucose”, Bull.
Acad. Sci. USSR, Div. Chem. Sci.,
1991, 40, No. 7, Part 1, 1317–1320.
116.
G. B. Shul’pin, A. N. Druzhinina, “Biomimetic activation of
the C–H bond. 2. Oxygenation of hydrocarbons with O2
catalyzed by porphyrin complexes of metals in the presence of
ferrocene as reducing agent”, Bull. Acad. Sci. USSR, Div. Chem.
Sci., 1991, 40, No. 12, Part 1, 2385–2389.
117.
M. M. Kats, Y. N. Kozlov, G. B.
Shul’pin, “Oxidation of benzene and cyclohexane in CH3CN–H2O
by means of XeO3 and XeF2”, J. Gen. Chem.
USSR, 1991,
61, No. 8, Part 2, 1694–1696.
118.
G. B. Shul’pin, A. N. Druzhinina, “Molybdenum hexacarbonyl
catalyzed photooxygenation of cyclohexane by air oxygen in CH3CN
solution”, React. Kinet. Catal. Lett., 1991, 44,
No. 2, 387–391.
119.
G. B. Shul’pin, G. V. Nizova,
“Contribution of air oxygen to photooxidation of alkanes by V(V) and
Cr(VI) oxocomplexes”, React.
Kinet. Catal. Lett., 1991, 45,
No. 1, 7–14.
120.
G. V. Nizova, G. V. Losenkova, G. B. Shul’pin, “Unusual
selectivity in photooxygenation of alkanes by air in CH3CN
solutions catalyzed by CrCl3 – C6H5CH2N(C2H5)3Cl”,
React. Kinet. Catal. Lett., 1991, 45, No. 1, 27–34.
121.
G. V. Nizova, J. Muzart, G. B. Shul’pin, “Cyclohexane
photooxygenation by air oxygen in CH2Cl2 in
the presence of chromium oxocomplex–iodosylbenzene system”,
React. Kinet. Catal. Lett., 1991, 45, No. 2, 173–178.
122.
P. Lederer, G. V. Nizova, M. M.
Kats, G. B. Shul’pin, “Photooxygenation of cyclohexane by dioxygen
in the presence of metal chlorides in acetonitrile <Part XIX in the
series “Photoinduced Reactions of Organic Compounds with Transition
Metal Complexes””, Coll. Czech.
Chem. Commun., 1992, 57, 107–112.
123.
G. B. Shul’pin, A. N. Druzhinina, “Iron(III) chloride
catalysed photooxygenation of alcohol solutions of alkanes by
atmospheric oxygen”, Mendeleev Commun., 1992, No. 1, 36–37.
124.
G. V. Nizova, G. B. Shul’pin,
“Photochemical oxidation of hydrocarbons by atmospheric oxygen in
solutions, catalysed by AuCl4– complex <Report
XXIV from series “Photoinitiated reactions of organic compounds with
transition metal complexes”” Petrol.
Chem., 1992,
32, No. 1, 36–41.
125.
J. Muzart, G. V. Nizova, A. Riahi, G. B. Shul’pin, “Oxidation
of alkanes by peroxide complexes of palladium”, J. Gen. Chem.
(Russia), 1992, 62, No. 5, 964.
126.
G. B. Shul’pin, A. N. Druzhinina, “Photooxidation of
cyclohexane by atmospheric oxygen in 2-propanol or methanol
catalyzed by FeCl3”, Bull. Russ. Acad. Sci., Div.
Chem. Sci., 1992, 41, No. 2, Part 2, 346–347.
127.
G. V. Nizova, B. Chaudret, X.-D. He, G. B. Shul’pin,
“Photochemical dehydrogenation of cyclohexane and its derivatives by
the cyclopentadienyl complexes of ruthenium with the formation of
pi-arene complexes of ruthenium(II)”, Bull. Russ. Acad. Sci.,
Div. Chem. Sci., 1992, 41, No. 6, Part 2, 1138.
128.
D. Attanasio, L. Suber, G. B. Shul’pin, “Photochemical
oxidation of hydrocarbons by a vanadium(V) peroxo complex”, Bull.
Russ. Acad. Sci., Div. Chem. Sci., 1992, 41, No.
8, Part 2, 1502–1504.
129.
G. B. Shul’pin, A. N. Druzhinina, “Hydroperoxidation of
alkanes by atmospheric oxygen in the presence of hydroquinone or
quinone catalyzed by copper(II) acetate under visible light
irradiation”, React. Kinet. Catal. Lett., 1992, 47,
No. 2, 207–211.
130.
G. B. Shul’pin, G. V. Nizova,
“Formation of alkyl peroxides in oxidation of alkanes by H2O2
catalyzed by transition metal complexes” React.
Kinet. Catal. Lett.,
1992, 48, No. 1, 333–338.
131.
G. B. Shul’pin, D. Attanasio, L.
Suber, “Efficient H2O2 oxidation of alkanes
and arenes to alkyl peroxides and phenols catalyzed by the system
vanadate – pyrazine-2-carboxylic acid”, J. Catal., 1993,
142, 147–152.
132.
G. B. Shul’pin, D. Attanasio, L. Suber, “Oxidations by a H2O2
– VO3– – pyrazine-2-carboxylic acid reagent.
1. Oxidations of alkanes in CH3CN to produce alkyl
peroxides”, Russ. Chem. Bull., 1993, 42, No. 1, 55–59.
133.
G. B. Shul’pin, A. N. Druzhinina,
G. V. Nizova, “Oxidation with the H2O2 – VO3–
– pyrazine-2-carboxylic acid reagent. 2. Oxidation of alcohols and
aromatic hydrocarbons”, Russ. Chem. Bull., 1993, 42,
No. 8, 1327–1329.
134.
G. B. Shul’pin, G. V. Nizova,
“Photo-oxidation of cyclohexane by atmospheric oxygen in
acetonitrile, catalysed by chloride complexes of iron, copper and
gold <Report XXV from series “Photoinitiated reactions of organic
compounds with metal complexes”” Petrol.
Chem., 1993,
33, No. 2, 107–112.
135.
J. Muzart, A. N. Druzhinina, G. B. Shul’pin,
“Photooxygenation of cyclohexane with air oxygen in methylene
chloride catalyzed by an oxo complex of chromium(IV) <Report XXVI
from series “Photoinitiated reactions of organic compounds with
metal complexes””, Petrol. Chem. (Russia), 1993, 33,
No. 2, 113–115.
136.
G. B. Shul’pin, A. N. Druzhinina,
“Oxidation of saturated hydrocarbons by air in acetonitrile in the
presence of molybdenum or tungsten carbonyls during light
irradiation) <Report XXVII from series “Photoinitiated reactions of
organic compounds with metal complexes””, Petrol.
Chem. (Russia),
1993, 33, No. 3, 247–251.
137.
G. B. Shul’pin, A. N. Druzhinina,
L. S. Shul’pina, “Photo-oxidation of cyclohexane by air in
acetonitrile, catalysed by pi-complexes of iron <Report XXVIII from
series “Photoinitiated reactions of organic compounds with metal
complexes””, Petrol. Chem.
(Russia), 1993, 33, No. 4,
321–325.
138.
G. Süss-Fink, G. B. Shul’pin, “The
oxidation of alkanols with air oxygen in the catalytic system
copper(II) acetate – hydroquinone promoted by visible light”,
Russ. Chem. Bull.,
1994, 43, No. 6, 1085–1086.
139.
G. V. Nizova, G. B. Shul’pin, “Oxidation by a H2O2
– vanadium complex – 2-pyrazinecarboxylic acid reagent. 3. Evidence
for hydroxyl radical formation”, Russ. Chem. Bull., 1994,
43, No. 7, 1146–1148.
140.
J. Vicente, A. Arcas, D. Bautista, G. B. Shul’pin, “Aerobic
photooxidation and C–C bond cleavage of the acetylacetonate ligand
in (2-arylazo)arylpalladium(II) complexes induced by visible light”,
J. Chem. Soc., Dalton Trans., 1994, No. 10, 1505–1509.
141.
G. V. Nizova, G. B. Shul’pin,
“Photo-oxidation of alkanes by atmospheric oxygen, catalysed a
vanadate–anthraquinone system <Report XXIX from series
“Photoinitiated reactions of organic compounds with metal
complexes””, Petrol. Chem.
(Russia), 1994, 34, No. 4,
353–356.
142.
G. B. Shul’pin, G. Süss-Fink
«Oxidations by the reagent “H2O2 – vanadium
complex – pyrazine-2-carboxylic acid”.
Part 4. Oxidation of alkanes, benzene and alcohols by an adduct of H2O2
with urea», J. Chem. Soc., Perkin Trans. 2, 1995, No. 7,
1459–1463.
143.
G. B. Shul’pin, M. M. Bochkova, G. V. Nizova, «Aerobic
oxidation of saturated hydrocarbons into alkyl hydroperoxides
induced by visible light and catalysed by a “quinone – copper
acetate” system”» <Part 30 of the series “Photoinduced Reactions of
Organic Compounds with Transition Metal Complexes”>, J. Chem.
Soc., Perkin Trans., 2, 1995, No. 7, 1465–1469.
144.
G. V. Nizova, M. M. Bochkova, N. B. Kozlova, G. B. Shul’pin,
«Photochemical aerobic detoxification of aqueous phenol and
chlorophenol solutions promoted by iron salts and iron, vanadium,
and copper oxides» <Part 31 of the series “Photoinduced Reactions of
Organic Compounds with Transition Metal Complexes”>, Russ. J.
Appl. Chem., 1995, 68, No. 3, Part 2, 448–451.
145.
G. B. Shul’pin, G. V. Nizova,
“Selective photochemical ketonization of cyclohexane by air in
aqueous emulsion in the presence of iron ions”, Mendeleev Commun.,
1995, No. 4, 143–145.
146.
C. Vicente, G. B. Shul’pin, B.
Moreno, S. Sabo-Etienne, B. Chaudret, “Reduction of ketones by
dihydrogen or hydrogen transfer catalysed by a ruthenium complex of
the hydridotris(3,5-dimethyl)pyrazolyl borate ligand”, J. Mol.
Catal.,
A: Chem., 1995, 98, L5–L8.
147.
G. V. Nizova, G. B. Shul’pin, “Alkane aerobic
photo-oxygenation sensitized by pyrazine derivatives”, Russ.
Chem. Bull., 1995, 44, No. 10, 1982–1983.
148.
M. M. Bochkova, G. B. Shul’pin,
"Photochemical decomposition of phenol and its derivatives in the
air in the presence of transition metal compounds.
Chemistry for Sustainable Development, 1996, 4, No. 1,
31–36.
149.
G. V. Nizova, G. B. Shul’pin, “Aerobic oxidation of
cumene photocatalyzed by iron salts”, Russ. Chem. Bull.,
1996, 45, No 6, 1353–1355.
150.
U. Schuchardt, D. Mandelli, G. B. Shul’pin,
“Methyltrioxorhenium catalyzed oxidation of saturated and aromatic
hydrocarbons by H2O2 in air”, Tetrahedron
Lett., 1996, 37, No 36, 6487–6490.
151.
G. B. Shul’pin, R. S. Drago, M. Gonzalez, “Oxidations by a “H2O2
– vanadium complex – pyrazine-2-carboxylic acid” reagent.
5. Oxidation of lower alkanes with the formation
of carbonyl compounds”, Russ.
Chem. Bull., 1996, 45, No. 10,
2386–2388.
152.
G. B. Shul’pin, M. C. Guerreiro, U. Schuchardt, “Oxidations
by the reagent O2 – H2O2 – vanadium
complex – pyrazine-2-carboxylic acid. Part 7. Hydroperoxidation of
higher alkanes”, Tetrahedron, 1996, 52, No 41,
13051–13062.
153.
G. B. Shul’pin, G. V. Nizova, Y. N.
Kozlov, «Photochemical aerobic oxidation of alkanes promoted by iron
complexes <Part 32 of the series “Photoinduced Reactions of Organic
Compounds with Metal Complexes”», New J. Chem., 1996, 20,
No 12, 1243–1256.
154.
G. B. Shul’pin, M. M. Bochkova, G.
V. Nizova, N. B. Kozlova, “Aerobic photodegradation of phenols in
aqueous solutions promoted by metal compounds” <Part 33
of the series “Photoinduced Reactions of Organic Compounds with
Metal Complexes”>, Appl. Catal.,
B: Environmental, 1997, 12, No.
1, 1–19.
155.
M. C. Guerreiro, U. Schuchardt, G.
B. Shul’pin,“ Oxidations by the reagent O2 – VO3–
– pyrazine-2-carboxylic acid. 6. Oxidation
of n-heptane. Direct GLC detection of formed alkyl
hydroperoxides”, Russ. Chem. Bull., 1997, 46, No 4,
749–754.
156.
G. V. Nizova, G. Süss-Fink,
G. B. Shul’pin, “Catalytic oxidation of methane to methyl
hydroperoxide and other oxygenates under mild conditions”, Chem.
Commun. 1997, 397–398.
157.
G. V. Nizova, G. Süss-Fink,
G. B. Shul’pin, “Oxidations by the reagent «O2 – H2O2
– vanadium complex – pyrazine-2-carboxylic acid» – 8. Efficient
oxygenation of methane and other lower alkanes in acetonitrile”,
Tetrahedron, 1997, 53, No. 10, 3603–3614.
158.
G. Süss-Fink,
H. Yan, G. V. Nizova, S. Stanislas, G. B. Shul’pin,“Oxygenation of
methane with atmospheric oxygen in aqueous solution promoted by H2O2
and catalyzed by a vanadate ion – pyrazine-2-carboxylic acid
system”, Russ. Chem. Bull.,
1997, 46, No. 10, 1801–1803.
159.
U. Schuchardt, M. C. Guerreiro, G. B. Shul’pin, «Oxidation
with the ‘O2 – H2O2 – vanadium
complex – pyrazine-2-carboxylic acid’ reagent. 9. Oxidation of
cyclohexene and decalin», Russ. Chem. Bull., 1998, 47,
No. 2, 247–252.
160.
G. Süss-Fink, G. V. Nizova, S. Stanislas, G. B. Shul’pin,
«Oxidations by the reagent ‘O2 – H2O2
– vanadate anion – pyrazine-2-carboxylic acid’.
Part 10. Oxygenation of methane in acetonitrile
and water», J. Mol. Catal., A:
Chem., 1998, 130, No. 1–2,
163–170.
161.
G. V. Nizova, G. Süss-Fink,
S. Stanislas, G. B. Shul’pin, “Carboxylation of methane with CO or
CO2 in aqueous solution catalysed by vanadium complexes”,
Chem. Commun.,
1998, 1885–1886.
162.
J. R. Lindsay Smith, G. B. Shul’pin, “Efficient
stereoselective oxygenation of alkanes by peroxyacetic acid or
hydrogen peroxide and acetic acid catalysed by a manganese(IV)
1,4,7-trimethyl-1,4,7-triazacyclononane complex”, Tetrahedron
Lett., 1998, 39, No. 27, 4909–4912.
163.
J. R. Lindsay-Smith, G. B. Shul’pin, “Oxidative
decarboxylation of cyclohexanecarbaldehyde in the presence of
cyclooctane catalyzed by a binuclear manganese(IV) complex”,
Russ. Chem. Bull., 1998, 47, No. 11, 2313–2315.
164.
G. B. Shul’pin, J. R.
Lindsay-Smith, «Oxidations by the reagent ‘H2O2
– manganese(IV) complex – carboxylic acid’.
Part 1. Oxidation of saturated hydrocarbons with
peroxy acids and hydrogen peroxide», Russ. Chem. Bull., 1998,
47, No. 12, 2379–2386.
165.
G. B. Shul’pin, G. Süss-Fink,
J. R. Lindsay Smith, “Oxidations by the system “Hydrogen Peroxide –
Manganese(IV) Complex – Acetic Acid”, Part II. Hydroperoxidation and
hydroxylation of alkanes in acetonitrile”, Tetrahedron, 1999,
55, No. 17, 5345–5358.
166.
G. B. Shul’pin, Y. Ishii, S. Sakaguchi, T. Iwahama,
“Oxidations with the “O2 – H2O2 –
vanadium complex – pyrazine-2-carboxylic acid” reagent. Part 11.
Oxidation of styrene, phenylacetylene, and their derivatives with
the formation of benzaldehyde and benzoic acid”, Russ. Chem. Bull.,
1999, 48, No. 5, 887–890.
167.
G. Süss-Fink,
S. Stanislas, G. B. Shul’pin, G. V. Nizova, H. Stoeckli-Evans, A.
Neels, C. Bobillier, S. Claude, “Oxidative functionalisation of
alkanes: synthesis, molecular structure and catalytic implications
of anionic vanadium(V) oxo and peroxo complexes containing bidentate
N,O ligands”, J. Chem. Soc., Dalton Trans., 1999, No.
18, 3169–3175.
168.
G. B. Shul’pin, G. Süss-Fink,
L. S. Shul’pina, “Oxygenation of alkanes with hydrogen peroxide
catalysed by osmium complexes”, Chem. Commun., 2000, No. 13,
1131–1132.
169.
G. Süss-Fink,
S. Stanislas, G. B. Shul’pin, G. V. Nizova, “Catalytic
functionalisation of methane”, Appl. Organometal. Chem.,
2000, 14, 623–628.
170.
G. B. Shul’pin, G. Süss-Fink,
L. S. Shul'pina, “Oxidative functionalisation of ethane with
hydrogen peroxide catalysed by chromic acid”, J. Chem. Res. (S),
2000, No. 12, 576–577.
171.
G. B. Shul’pin, G. Süss-Fink,
L. S. Shul'pina, «Oxidations by the system "hydrogen peroxide –
manganese(IV) complex – carboxylic acid". Part 3. Oxygenation of
ethane, higher alkanes, alcohols, olefins and sulfides»,
J. Mol. Catal., A: Chem.,
2001, 170, No. 1-2, 17–34.
172.
Y. N. Kozlov, G. V. Nizova, G. B. Shul’pin, "The mechanism of
hydrogen peroxide-induced aerobic oxidation of alkanes in catalysis
by a vanadium complex and pyrazine-2-carboxylic acid", Russ. J.
Phys. Chem., 2001,
75, No. 5, 770–774
.
173.
G. Süss-Fink, L. Gonzalez, G. B. Shul’pin, «Alkane oxidation
with hydrogen peroxide catalyzed homogeneously by
vanadium-containing polyphosphomolybdates », Appl. Catal., A:
General., 2001, 217, No. 1–2, 111–117.
174.
G. B. Shul’pin, Y. N. Kozlov, G. V. Nizova, G. Süss-Fink, S.
Stanislas, A. Kitaygorodskiy, V. S. Kulikova, «Oxidations by
the reagent "O2 – H2O2 – vanadium
derivative – pyrazine-2-carboxylic acid" Part 12.
Main features, kinetics and mechanism of alkane
hydroperoxidation», J. Chem. Soc.,
Perkin Trans. 2, 2001, No. 8,
1351–1371. Electronic supplementary information (ESI) available:
Appendix 1. On the possibility of radical-chain oxygenation of
alkanes. Appendix 2. Comparison with other alkane-oxygenating
systems. Additional references. See
http://www.rsc.org/suppdata/p2/b1/b101442k/
.
175.
G. B. Shul’pin, “Oxidation of
saturated hydrocarbons with tert-butyl hydroperoxide
catalyzed by manganese complexes”,
Petrol. Chem., 2001, 41, No. 6,
405–412.
176.
G. B. Shul’pin, G. Süss-Fink, A. E. Shilov, "Alkane
oxygenation catalysed by gold complexes", Tetrahedron Lett.,
2001, 42, 7253–7256.
177.
G. Süss-Fink, G. B. Shul’pin, “Hydrogen hydroperoxide
oxidation of ethane and other alkanes catalyzed by chromium
compounds”, Petrol. Chem. (Russia), 2002, 42, No. 1,
15–19.
178.
G. B. Shul’pin, G. Süss-Fink, “Hydrogen peroxide oxidation of
saturated hydrocarbons catalyzed by osmium compounds”, Petrol.
Chem. (Russia), 2002, 42, No. 4, 233–237.
179.
G. B. Shul’pin, "Alkane oxygenation
with hydrogen peroxide catalysed by soluble derivatives of nickel
and platinum", J. Chem. Res. (S),
2002, No. 7, 351–353.
180.
B. Therrien, S. Stanislas, H. Stoeckli-Evans, G. B. Shul'pin,
G. Süss-Fink, "Bis(tetrabutylammonium)
bis(malonato)oxovanadate(IV)", Acta Cryst., 2002, E58,
No. 5, m215–m216.
181.
D. Mandelli, C. B. Woitiski, U. Schuchardt, G. B. Shul’pin,
"Hydrogen-peroxide epoxidation of natural olefins catalyzed by a
dinuclear manganese complex", Chem. Natur. Comp., 2002, 38,
No. 3, 243–245.
182.
G. B. Shul’pin, G. V. Nizova, Y. N. Kozlov, I. G. Pechenkina,
«Oxidations by the "hydrogen peroxide–manganese(IV)
complex–carboxylic acid" system. Part 4.
Efficient acid-base switching between catalase and oxygenase
activities of a dinuclear manganese(IV) complex in the reaction with
H2O2 and an alkane»,
New J. Chem., 2002,
26, No. 9, 1238–1245.
183.
G. V. Nizova, C. Bolm, S.
Ceccarelli, C. Pavan, G. B. Shul’pin, "Hydrocarbon oxidations with
hydrogen peroxide catalyzed by a soluble polymer-bound manganese(IV)
complex with 1,4,7-triazacyclononane",
Adv. Synth. Catal., 2002, 344,
No. 8, 899–905.
184.
G. V. Nizova, B. Krebs, G. Süss-Fink, S. Schindler, L.
Westerheide, L. Gonzalez Cuervo, G. B. Shul’pin, "Hydroperoxidation
of methane and other alkanes with H2O2
catalysed by a dinuclear iron complex and an amino acid",
Tetrahedron, 2002, 58, No. 45, 9231–9237.
185.
G. B. Shul’pin,
E. R. Lachter, "Aerobic hydroxylation of hydrocarbons catalysed by
vanadate ion", J. Mol. Cat., A: Chem., 2003, 197, No.
1–2, 65–71.
186.
M. H. C. de la Cruz, Y. N. Kozlov,
E. R. Lachter, G. B. Shul’pin, "Oxidations by the reagent “O2
– H2O2 – vanadium derivative –
pyrazine-2-carboxylic acid”. Part 13. Kinetics
and mechanism of the benzene
hydroxylation",
New J. Chem., 2003, 27, No. 3, 634–638.
187.
M. Vennat, P. Herson, J.-M. Brégeault,
G. B. Shul’pin,
"Vanadium-catalysed aerobic cleavage of C–C
bonds in substituted cyclohexanones to afford carboxylic acids: two
model complexes with tetrahedral geometry around vanadium(V)",
Eur. J. Inorg. Chem., 2003, No. 5, 908–917.
188.
Y. N. Kozlov, L. Gonzalez-Cuervo, G. Süss-Fink,
G. B. Shul’pin, "The kinetics and mechanism of cyclohexane
oxygenation by hydrogen peroxide catalyzed by a binuclear iron
complex", Russ. J. Phys. Chem., 2003, 77,
No. 4, 575–579.
189.
G. B. Shul’pin,
Y. N. Kozlov, "Kinetics and mechanism of alkane hydroperoxidation
with tert-butyl hydroperoxide catalysed by a vanadate ion", Org.
Biomol. Chem., 2003, 1, No. 13, 2303–2306.
190.
G. B. Shul’pin, J. Gradinaru, Y. N. Kozlov, "Alkane
hydroperoxidation with hydroperoxides catalysed by copper
complexes", Org. Biomol. Chem., 2003, 1, No. 20,
3611–3617.
191.
G. B. Shul’pin,
"Metal-Catalyzed Hydrocarbon Oxidations",
ChemInform, 2003,
34, No. 37 (September 16).
192.
G. B. Shul’pin,
"Metal-Catalyzed Hydrocarbon Oxygenations in Solutions: The Dramatic
Role of Additives", ChemInform,
2003, 34, No. 38 (September 23).
193.
Y. N. Kozlov, G. V. Nizova, G. B. Shul’pin,
"The nature of oxidizing particles in the catalytic decomposition of
H2O2 with Fe(III) salts in acetonitrile",
Russ. J. Phys. Chem., 2004, 78, No. 2, 184–187.
194.
Y. N. Kozlov, D. Mandelli, C. B. Woitiski, G. B. Shul’pin,
"Mechanism of the oxidation of olefins and alkanes with a H2O2
– dimeric Mn(IV) complex – acetic acid system", Russ. J.
Phys. Chem., 2004, 78, No. 3, 370–374.
195.
L. Gonzalez Cuervo, Y. N. Kozlov, G. Suss-Fink, G. B.
Shul’pin, “Oxidation of saturated hydrocarbons with peroxyacetic
acid catalyzed by vanadium complexes”, J. Mol. Catal. A:
Chem., 2004, 218, No. 2, 171–177.
196.
G. B. Shul’pin, H. Stoeckli-Evans, D.
Mandelli, Y. N. Kozlov, A. Tesouro Vallina, C.B. Woitiski, R.S.
Jimenez, W.A. Carvalho, “Oxidation of alkanes with m-chloroperbenzoic
acid catalyzed by iron(III) chloride and a polydentate amine”, J.
Mol. Catal. A: Chem., 2004, 219, No. 2, 255–264.
197.
C. B.
Woitiski, Y.
N. Kozlov,
D. Mandelli,
G.
V.
Nizova,
U. Schuchardt,
G. B.
Shul’pin,
“Oxidations
by the
system
“hydrogen peroxide–dinuclear
manganese(IV)
complex–carboxylic
acid”.
Part
5.
Epoxidation
of olefins
including
natural
terpenes”,
J.
Mol. Catal.
A: Chem.,
2004, 222, No. 1–2, 103–119.
198.
G. B.Shul’pin,
G. V.
Nizova, Y.
N. Kozlov,
L. Gonzalez Cuervo,
G. Süss-Fink,
“Hydrogen peroxide oxygenation of alkanes
including methane and ethane catalyzed by iron complexes in
acetonitrile”, Adv. Synth. Catal., 2004, 346, No. 2–3,
317–332.
199.
G. Süss-Fink, L. Gonzalez Cuervo,
B. Therrien, H. Stoeckli-Evans, G. B. Shul’pin, “Mono and
oligonuclear vanadium complexes as catalysts for alkane oxidation:
synthesis, molecular structure and catalytic potential”, Inorg.
Chim. Acta., 2004, 357, No. 2, 475–484.
200.
G. V. Nizova, Y. N. Kozlov, G. B. Shul’pin, "Effect of
acetonitrile on the catalytic decomposition of hydrogen peroxide by
vanadium ions and conjugated oxidation of alkanes", Russ. Chem.
Bull., 2004, No. 10, 2330–2333.
201.
G. B. Shul’pin,
"Metal-Catalyzed Hydrocarbon Oxidations",
ChemInform, 2004,
35, No. 12 (March 23).
202.
Y. N. Kozlov, G. V. Nizova, G. B.
Shul’pin, “Oxidations by the reagent “O2–H2O2–vanadium
derivative–pyrazine-2-carboxylic acid”. Part 14. Competitive
oxidation of alkanes and acetonitrile (solvent)”, J. Mol. Catal.
A: Chem., 2005, 227, No. 1–2,
247–253.
203.
G. B.
Shul’pin,
G. V.
Nizova, Y.
N. Kozlov,
V. S.
Arutyunov, A.
C. M.
dos Santos, A.
C. T.
Ferreira, D.
Mandelli, "Oxidations
by the system ‘‘hydrogen peroxide–[Mn2L2O3][PF6]2
(L = 1,4,7-trimethyl-1,4,7-triazacyclononane)–oxalic
acid’’. Part 6. Oxidation of methane and
other alkanes and olefins in water", J. Organometal. Chem.,
2005, 690, No. 20, 4498–4504.
204.
G. B.
Shul’pin,C. C.
Golfeto, G.
Süss-Fink,
L. S.
Shul’pina,
D. Mandelli, "Alkane
oxygenation with H2O2
catalysed by FeCl3
and 2,2’-bipyridine",
Tetrahedron Lett., 2005, 46,
No. 27, 4563–4567.
205.
L. S.
Shul’pina,
A. R.
Kudinov, G.
Süss-Fink,
D. A.
Loginov, G.
B. Shul’pin,
"Oxidation of saturated hydrocarbons with
peroxides catalyzed by iridium and palladium complexes",
Petrol. Chem.,
2005, 45, No. 5, 309–311.
206.
M. J.
D. M.
Jannini, L.
S. Shul’pina,
U. Schuchardt,
G. B.
Shul’pin, "Oxidation
of alkanes with hydrogen peroxide catalyzed by the "vanadate-ion–pyrazine-2-carboxylic
acid" system in the presence of pyridine"
(Part 15 of the series
"Oxidations by the reagent O2–H2O2–vanadium
derivative–pyrazine-2-carboxylic
acid"), Petrol.
Chem., 2005, 45,
No. 6, 413–418.
207.
G. B. Shul’pin,
"Oxidations of C–H Compounds Catalyzed by Metal Complexes", ChemInform,
2005, 36, No. 41 (October 11).
208.
G. B. Shul’pin, A. R. Kudinov, L. S.
Shul’pina, E. A. Petrovskaya, "Oxidations
catalyzed by osmium compounds. Part 1: Efficient alkane oxidation
with peroxides catalyzed by an olefin carbonyl osmium(0) complex",
J. Organometal. Chem., 2006, 691, 837–845.
209.
L. S.
Shul’pina,
D. Veghini,
A. R.
Kudinov, G.
B. Shul’pin,
"Oxidation of alcohols with hydrogen peroxide
catalysed by soluble iron and osmium derivatives",
React. Kinet.
Catal. Lett., 2006, 88,
No. 1, 157–164.
210.
D. Mandelli,
R. A.
Steffen, G.
B. Shul’pin,
Carvone epoxidation by the system "Hydrogen
peroxide – [Mn2L2O3][PF6]2 (L =1,4,7-trimethyl-1,4,7-triazacyclononane)
–carboxylic acid":
a combinatorial approach to the process
optimization" <Part 7 from the series “Oxidations
by the system hydrogen peroxide–[Mn2L2O3][PF6]2
(L =1,4,7-trimethyl-1,4,7-triazacyclononane)–carboxylic acid”>, React.
Kinet. Catal.
Lett., 2006, 88, No. 1,
165–174.
211.
L. S.
Shul’pina,
A. R.
Kudinov, E.
A. Petrovskaya,
T. V.
Strelkova, G.
B. Shul’pin,
"Hydrogen peroxide oxidation of alkanes catalyzed
by the osmium complex Os3(CO)11(eta2-PhCOCH=CHCOPh)",
Petrol. Chem.
, 2006, 46, No. 3, 164–166.
212.
D. Veghini,
L. S.
Shul’pina,
T. V.
Strelkova, G.
B. Shul’pin,
"Hydrogen peroxide oxidation of 2-cyanoethanol
catalyzed by metal-complexes",
Petrol. Chem.,
2006, 46, No. 3, 167–170.
213.
V. A.
dos Santos
, L. S.
Shul’pina,
D. Veghini,
D. Mandelli,
G. B.
Shul’pin, "Highly efficient
oxidation
of
alcohols
by
the
system
“hydrogen
peroxide–[LMn(O)3MnL](PF6)2
(L = 1,4,7-trimethyl-1,4,7-triazacyclononane)–oxalic
acid”
<Part 8 from the series “Oxidations
by the system hydrogen peroxide–[Mn2L2O3][PF6]2
(L =1,4,7-trimethyl-1,4,7-triazacyclononane)–carboxylic acid”> , React. Kinet. Catal. Lett., 2006,
88, No. 2, 339–348.
214.
G. B.
Shul’pin,
T. Sooknoi,
V. B.
Romakh, G.
Süss-Fink,
L. S.
Shul’pina, "Regioselective
alkane oxygenation with H2O2
catalyzed by titanosilicalite TS-1",
Tetrahedron Lett., 2006, 47,
No. 18, 3071–3075.
215.
V. B.
Romakh, B.
Therrien, L.
Karmazin-Brelot,
G. Labat,
H. Stoeckli-Evans,
G. B.
Shul’pin,
G. Süss-Fink,
"Dinuclear manganese complexes containing
1,4-dimethyl-1,4,7-triazacyclononane
ligands as well as carboxylato and oxo bridges",
Inorg. Chim. Acta,
2006, 359, No. 5, 1619–1626.
216.
V. B.
Romakh, B.
Therrien, G.
Labat, H.
Stoeckli-Evans,
G. B.
Shul’pin,
G. Süss-Fink,
"Dinuclear iron,
ruthenium and cobalt complexes containing 1,4-dimethyl-1,4,7-triazacyclononane
ligands as well as carboxylato and oxo or hydroxo bridges",
Inorg. Chim.
Acta, 2006, 359,
No. 10, 3297–3305.
217.
V. B. Romakh, B. Therrien, G.
Süss-Fink, G. B. Shul’pin, "Dinuclear
manganese complexes containing chiral
1,4,7-triazacyclononane-derived ligands and their catalytic
potential for the oxidation of olefins, alkanes, and alcohols",
Inorg. Chem., 2007, 46, No. 4, 1315–1331.
218.
G.
B.
Shul’pin,
G.
S.
Mishra,
L.
S.
Shul’pina,
T.
V.
Strelkova,
A.
J.
L.
Pombeiro, "Oxidation
of hydrocarbons with hydrogen peroxide catalyzed by maltolato
vanadium complexes covalently bonded to silica gel",
Catal.
Commun., 2007,
8, 1516–1520.
219.
V. B.
Romakh, B.
Therrien, G.
Süss-Fink,
G. B.
Shul’pin, "Synthesis,
molecular structure and catalytic potential of
the tetrairon complex [Fe4(N3O2-L)4(μ-O)2]4+
(L = 1-carboxymethyl-4,7-dimethyl-1,4,7-triazacyclononane)",
Inorg. Chem.,
2007, 46, No. 8, 3166–3175.
220.
V. B.
Romakh, Y.
N. Kozlov,
G. Süss-Fink,
G. B.
Shul’pin, “The
Kinetics and Mechanism of Oxidation of Isopropanol with the Hydrogen
Peroxide–Vanadate Ion–Pyrazine-2-Carboxylic
Acid System”, Russ.
J. Phys.
Chem. A,
2007, 81, No. 8, 1221–1229.
221.
Y. N.
Kozlov, V.
B. Romakh,
A. Kitaygorodskiy,
P. Buglyó,
G. Süss-Fink,
G. B.
Shul’pin, “Oxidation
of 2-Propanol and Cyclohexane by the
Reagent “Hydrogen Peroxide-Vanadate
Anion-Pyrazine-2-carboxylic
Acid”: Kinetics and Mechanism” <Part
16 of the series “Oxidations by the Reagent ‘H2O2-Vanadium
Derivative-Pyrazine-2-carboxylic Acid’”>, J.
Phys. Chem.
A, 2007, 111, 7736–7752.
DOI 10.1021/jp0700884
222.
D. Mandelli,
Y. N.
Kozlov, C. C.
Golfeto, G.
B. Shul’pin,
“Peroxyacetic Acid Oxidation of Olefins and
Alkanes Catalyzed by a Dinuclear Manganese(IV)
Complex with 1,4,7-trimethyl-1,4,7-triazacyclononane”,
Catal. Lett.,
2007, 118, 22–29.
223.
G. V.
Nizova, G.
B. Shul’pin,
“A unique rate-accelerating
effect of certain amino acids in the H2O2
oxidation of alkanes catalyzed by a dinuclear
manganese complex containing 1,4,7-trimethyl-1,4,7-triazacyclononane”<Part
9 from the series “Oxidations
by
the
system
‘hydrogen peroxide–[Mn2L2O3][PF6]2
(L
=1,4,7-trimethyl-1,4,7-triazacyclononane)–carboxylic
acid’”>",
Tetrahedron, 2007, 63,
No. 33, 7997–8001.
224.
G. B. Shul’pin, T. Sooknoi, L. S.
Shulpina, “The Influence of Organic Additives on the
Regioselectivity of Oxygenation of Alkanes with Hydrogen Peroxide in
the Presence of TS-1 Titanium Silicalite”, Petrol. Chem.,
2008, 48, No. 1, 36–39.
225.
L. S.
Shul’pina,
K. Takaki,
T. V.
Strelkova, G.
B. Shul’pin,
“Benzene Oxidation with Hydrogen Peroxide
Catalyzed by Soluble and Heterogenized Copper Compounds”,
Petrol. Chem.,
2008, 48, No. 3, 219–222.
226.
V. B. Romakh, G. Süss-Fink, G. B. Shul’pin, “Vanadate
Ion-Catalyzed Oxidation of Methane with Hydrogen Peroxide in an
Aqueous Solution”, Petrol. Chem., 2008, 48, No. 6, 440–443.
227.
G. B. Shul’pin, D. V. Muratov, L. S. Shul’pina, A. R.
Kudinov, T. V. Strelkova, P. V. Petrovskiy, “Oxygenation of aromatic
hydrocarbons with hydrogen peroxide catalyzed by rhodium carbonyl
complexes”, Appl. Organometal. Chem., 2008, 22, 684–688.
228.
G. B. Shul’pin, M. V. Kirillova, T. Sooknoi, A. J. L.
Pombeiro, “Oxidation of Saturated Hydrocarbons to Alkyl
Hydroperoxides by a ‘H2O2/Titanosilicalite-1/NaOH/MeCN’
System”, Catal. Lett. 2008, 128, 135–141.
229.
D. Mandelli, K. C. Chiacchio, Y. N. Kozlov, G. B. Shul’pin,
“Hydroperoxidation of alkanes with hydrogen peroxide catalyzed by
aluminium nitrate in acetonitrile”,
Tetrahedron Lett., 2008, 49,
6693–6697.
230.
Y. N. Kozlov, G. V. Nizova, G. B. Shul’pin, “Alkane oxidation
by the system ‘tert-butyl hydroperoxide–[Mn2L2O3][PF6]2
(L = 1,4,7-trimethyl-1,4,7-triazacyclononane)–carboxylic acid’,
J. Phys. Org. Chem., 2008, 21, 119–126.
231.
G. B. Shul’pin, M. G. Matthes, V. B. Romakh, M. I. F.
Barbosa, J. L. T. Aoyagi, D. Mandelli, “Oxidations by the system
‘hydrogen peroxide–[Mn2L2O3][PF6]2
(L = 1,4,7-trimethyl-1,4,7-triazacyclononane)–carboxylic acid’. Part
10: Co-catalytic effect of different carboxylic acids in the
oxidation of cyclohexane, cyclohexanol, and acetone”,
Tetrahedron, 2008,
64, 2143–2152.
232.
G. B. Shul’pin, Y. N. Kozlov, S. N. Kholuiskaya, M. I.
Plieva, “Oxidations by the system ‘hydrogen peroxide–[Mn2L2O3]2+
(L = 1,4,7-trimethyl-1,4,7-triazacyclononane)–oxalic acid’. Part 11.
Degradation of dye Rhodamine 6G and oxygenation of cyclohexene”,
J. Mol. Catal. A: Chem., 2009, 299, 77–87.
233.
L. S.
Shul’pina, M. V. Kirillova, A. J. L. Pombeiro, G. B. Shul’pin, “Alkane
oxidation by the H2O2–NaVO3–H2SO4
system in acetonitrile and water”,
Tetrahedron, 2009, 65, 2424–2429.
234.
D. Mandelli,
A.
C. N. do Amaral,
Y.
N. Kozlov,
L. S. Shul’pina,
A. J. Bonon,
W.
A. Carvalho,
G. B. Shul’pin,
“Hydrogen Peroxide Oxygenation
of Saturated and Unsaturated Hydrocarbons Catalyzed by
Montmorillonite or Aluminum Oxide”, Catal. Lett.,
2009, 132,
235–243.
235.
A. J. Bonon, D. Mandelli, O. A. Kholdeeva, M. V. Barmatova,
Y. N. Kozlov, G. B. Shul’pin, “Oxidation of alkanes and olefins with
hydrogen peroxide in acetonitrile solution catalyzed by a mesoporous
titanium-silicate Ti-MMM-2”, Appl. Catal. A: General, 2009,
365,
96–104.
236.
M. V. Kirillova, M. L. Kuznetsov,
V. B. Romakh, L. S. Shul’pina, J. J. R. Fraústo da Silva, A. J. L.
Pombeiro, G. B. Shul’pin, “Mechanism of
oxidations with H2O2 catalyzed by vanadate
anion or oxovanadium(V)
triethanolaminate (vanadatrane) in combination with
pyrazine-2-carboxylic acid (PCA): Kinetic and DFT studies”, J.
Catal., 2009, 267, 140–157.
237.
M. V. Kirillova, Y. N. Kozlov, L. S.
Shul’pina, O. Y. Lyakin, A. M. Kirillov, E. P. Talsi, A. J. L.
Pombeiro, G. B. Shul’pin, “Remarkably
fast oxidation of alkanes by hydrogen peroxide catalyzed by a
tetracopper(II) triethanolaminate complex: Promoting effects of acid
co-catalysts and water, kinetic and mechanistic features”,
J. Catal., 2009, 268, 26–38.
238.
G. B. Shul’pin, Y. N. Kozlov, L. S. Shul’pina, A. R. Kudinov,
D. Mandelli, “Extremely Efficient Alkane Oxidation by a New
Catalytic Reagent H2O2/Os3(CO)12/Pyridine”,
Inorg. Chem., 2009, 48, No. 22,
10480–10482.
239.
G. B.
Shul’pin, Y. N. Kozlov, L. S. Shul’pina, P. V. Petrovskiy,
“Oxidation of alkanes and alcohols with hydrogen peroxide catalyzed
by complex Os3(CO)10(mu-H)2” <Part
2 of the series ‘Oxidations catalyzed by osmium compounds’>,
Appl. Organometal.
Chem.,
2010, 24,
464–472. DOI 10.1002/aoc.1641
240.
M.
V.
Kirillova,
A.
M.
Kirillov,
D.
Mandelli,
W.
A.
Carvalho,
A.
J.
L.
Pombeiro,
G.
B.
Shul’pin,
”Mild homogeneous
oxidation of
alkanes and
alcohols including
glycerol with
tert-butyl hydroperoxide
catalyzed by
a
tetracopper(II)
complex”,
J.
Catal.,
2010, 272, 9–17.
241.
G. B.
Shul’pin,
Y. N.
Kozlov, L.
S. Shul’pina,
T. V.
Strelkova, D.
Mandelli, “Oxidation of
Reactive Alcohols with Hydrogen Peroxide Catalyzed by Manganese
Complexes” <Part 12
from the series ‘‘Oxidations
by the system ‘hydrogen peroxide–[Mn2L2O3]2+
(L = 1,4,7-trimethyl-1,4,7-triazacyclononane)–carboxylic
acid’’’>, Catal.
Lett., 2010, 138, No. 3–4,
193–204.
242.
Y. N.
Kozlov, L. S.
Shul’pina,
T. V.
Strelkova, G.
B. Shul’pin,
“Kinetics and Mechanism of 1-Phenylethanol
Oxidation by the System Hydrogen Peroxide–Manganes(IV)
Binuclear Complex–Oxalic
Acid”, Russ.
J. Phys. Chem.
A, 2010, 84,
No. 9, 1502–1505.
243.
G. B. Shul’pin, M. V. Kirillova, Y. N. Kozlov, L. S.
Shul’pina, A. R. Kudinov, A. J. L. Pombeiro,
“Decamethylosmocene-catalyzed efficient oxidation of saturated and
aromatic hydrocarbons and alcohols with hydrogen peroxide in the
presence of pyridine” <Part 3 from the series ‘‘Oxidations Catalyzed
by Osmium Compounds’’>, J. Catal., 2011, 277, No. 2,
164–172. DOI: 10.1016/j.jcat.2010.11.002
244.
M. L. Kuznetsov, Y. N. Kozlov, D. Mandelli, A. J. L.
Pombeiro, G. B. Shul’pin, “Mechanism of Al3+-Catalyzed
Oxidations of Hydrocarbons: Dramatic Activation of H2O2
toward O–O Homolysis in Complex [Al(H2O)4(OOH)(H2O2)]2+
Explains the Formation of HO• Radicals”, Inorg. Chem.,
2011, 50, 3996–4005. DOI: dx.doi.org/10.1021/ic102476x
245.
A. M. Kirillov, M. V. Kirillova, L. S. Shul’pina, P. J.
Figiel, K. R. Gruenwald, M. F. C. G. da Silva, M. Haukka, A. J. L.
Pombeiro, G. B. Shul’pin, “Mild
oxidative functionalization of alkanes and alcohols catalyzed by new
mono- and dicopper(II) aminopolyalcoholates”, J. Mol.
Catal. A: Chem., 2011, in press.
246.
M. V. Kirillova, M. L. Kuznetsov, Y. N. Kozlov,
L. S. Shul’pina, A. Kitaygorodskiy, A. J. L. Pombeiro, G. B.
Shul’pin, “Participation of Oligovanadates in Alkane Oxidation with
H2O2 Catalyzed by Vanadate-anion in Acidified
Acetonitrile: Kinetic and DFT Studies”, ACS Catal. 2011, 1,
in press.
Selected Patents in
English
247.
A. N. Nesmeyanov, M. I. Rybinskaya, G. B. Shul’pin, “Method
for isolating organometallic compounds and
thiourea adducts with organometallic compounds”, Pat.
USA 3,950,373,
1976.
248.
A. N. Nesmeyanov, M. I. Rybinskaya,
G. B. Shul’pin, “Adducts of organometallic compounds with thiourea”,
Pat. UK 1457605,
1976.
249.
A. Hoehn, G. Suess-Fink, G. B.
Shulpin, G. V. Nizova, "Oxidation of methane and ethane to products
containing carbon, hydrogen and oxygen in the presence of metal
complexes", Ger. Offen. DE
19,720,344, 1997 (to BASF A.–G.,
Germany), 5 pp. Application: DE 97-19720344 19970515. (Chem.
Abstr. 128:48802p, 1998).
250.
G. Suess-Fink, G. B. Shul’pin,
L. S. Shul’pina,
"Process for the
production of ketones",
Pat.
USA
7,015,358 (March 21, 2006; Filled 2002, to Lonza
A.–G., Switzerland). Eur.
Pat.
EP 1 385 812 A0 (Application: WO 02/088063, art.
158 of the EPC).
Selected Abstracts and Proceedings
of Conferences
251.
C.
B. Woitiski, Y. N. Kozlov, G. V. Nizova, U. Schuchardt, D. Mandelli,
G. B. Shul’pin, “Epoxidation of olefins including natural terpenes
by the system ‘hydrogen peroxide–manganese(IV) complex–carboxylic
acid’ in acetonitrile.
Kinetics and mechanism of the dec-1-ene epoxidation”, Proceedings
of the 13th International Congress on Catalysis, Paris, France,
2004, oral presentation O2-009.
252.
R. A. Steffen, G. B. Shul’pin, D. Mandelli, “A combinatorial
approach to the optimization of carvone epoxidation by the ‘hydrogen
peroxide–manganese(IV) complex–oxalic acid’ system”, Proceedings
of the 13th International Congress on Catalysis, Paris, France,
2004, poster presentation P3-061.
253.
G. B. Shul’pin, G. V. Nizova, Y. N. Kozlov, V. S. Arutyunov,
A. C. M. dos Santos, A. C. da Silva, D. Mandelli, “Oxidation of
Hydrocarbons Including Methane by the ‘Hydrogen
Peroxide–Manganese(IV) Complex–Oxalic Acid’ System in Water: Unusual
Regio-selectivity in the Reaction with n-Heptane”,
Proceedings of the 14th International Symposium on Homogeneous
Catalysis, Munich, Germany, 2004, page 230.
254.
D. Mandelli, H. Stoeckli-Evans, Y. N. Kozlov, A.
Tesouro Vallina, C. B. Woitiski, R. S. Jimenez, W. A. Carvalho, G.
B. Shul’pin, “Oxidation of Alkanes with m-Chloroperbenzoic
Acid Catalyzed by Iron(III) Chloride and a Polydentate N4-Amine”,
Proceedings of the 14th International Symposium on Homogeneous
Catalysis, Munich, Germany, 2004, page 227.
255.
C. C. Golfeto, D. Mandelli, Y. N. Kozlov, G. B.
Shul’pin, “Peroxyacetic Acid Oxidation of Hydrocarbons Catalyzed by
a Manganese(IV) Complex with
1,4,7-Trimethyl-1,4,7-triazacyclononane”, Proceedings of the 14th
International Symposium on Homogeneous Catalysis, Munich,
Germany, 2004, page 226.
256.
V. A. dos Santos, D. Mandelli, M. I. F. Barbosa, G. B.
Shul’pin, “Highly Efficient Oxidation of Secondary Alcohols with H2O2
Catalyzed by a Dinuclear Manganese(IV)
Complex and Oxalic Acid”, Proceedings of the 14th International
Symposium on Homogeneous Catalysis, Munich, Germany, 2004, page
229.
257.
D. Mandelli, M. I. F. Barbosa, M. G. Matthes,
J. L. T. Aoyagi, B. L. Tacarambi,
G. B.
Shul’pin, “Oxidation of alkanes and alcohols by the
system “hydrogen peroxide – [(TMTACN)2Mn2(O)3](PF6)2
(TMTACN = 1,4,7-trimethyl-1,4,7-triazacyclononane) – carboxylic
acid”, Proceedings of XX Ibero-American Symposium on Catalysis,
Gramado, Brazil, 2006, poster P-317, page 267.
258.
D. Mandelli, C. C. Golfeto, L. S. Shul’pina,
G. B.
Shul’pin, “Alkane oxygenation with H2O2
catalysed by FeCl3 and 2,2'-bipyridine”, Proceedings
of the XX Ibero-American Symposium on Catalysis, Gramado,
Brazil, 2006, oral presentation B-01, page 90.
259.
M. V. Kirillova, L. S. Shul’pina,
T. Sooknoi, A. J. L. Pombeiro, G. B. Shul’pin, “Alkane oxygenation
with H2O2 catalysed by Silicalite TS-1”,
Abstracts of the 3rd International
Conference on Green and Sustainable Chemistry,
Delft, The Netherlands, 2007.
260.
D. Mandelli, M. G. Matthes, J. L. T. Aoyagi,
G. B.
Shul’pin, “Hydrogen peroxide oxidation of organic compounds
catalyzed by manganese complexes with
1,4,7-trimethyl-1,4,7-triazacyclononane in the presence of a
carboxylic acid”,
Abstracts of 3rd International Conference “Catalysis: fundamentals
and application”, 2007,
Novosibirsk, Russia., oral presentation OP-I-12, vol. 1, page 82.
261.
D. Mandelli, L. S. Shul’pina, C. C. Golfeto, G. B. Shul’pin,
“Hydrogen peroxide oxidation of saturated hydrocarbons catalyzed by
iron(III) chloride and 2,2’-bipyridine”, Abstracts of 3rd
International Conference “Catalysis: fundamentals and application”,
2007, Novosibirsk, Russia. PP-I-33, vol. 2, page 67.
262.
G. B. Shul’pin, “Free-radical, crypto-radical and non-radical
metal-catalyzed alkane oxygenations by peroxides”, Extended
Abstracts of the 14th International Congress on Catalysis,
Seoul, Korea, 2008, Abstract PIII-51-10, PICC08-0285.
263.
G. B. Shul’pin, D. V. Muratov, L. S. Shul’pina, A. R. Kudinov,
“Oxygenation of benzene with H2O2 in
acetonitrile solution catalyzed by rhodium carbonyl complexes”,
Extended Abstracts of the 14th International Congress on Catalysis,
Seoul, Korea, 2008, Abstract PIII-53-12, PICC08-0288(1).
264.
D. Mandelli, Y. N. Kozlov, A. C. N. do Amaral, R. Bogarin, A.
J. Bonon, W. A. Carvalho, J. L. T. Aoyagi, G. B. Shul’pin, “
Hydrocarbon oxidation with H2O2 catalyzed by
alumina or montmorillonite”, Extended Abstracts of the 14th
International Congress on Catalysis, Seoul, Korea, 2008,
Abstract PIII-53-14, PICC08-0306.
265.
D. Mandelli, O. A. Kholdeeva, A. J. Bonon, M. V. Barmatova,
G. B. Shul’pin, “Hydrogen peroxide oxygenation of saturated
hydrocarbons in acetonitrile catalyzed by mesoporous
titanium-silicate Ti-MMM-2”, Extended Abstracts of the 14th
International Congress on Catalysis, Seoul, Korea, 2008,
Abstract PIII-53-15, PICC08-0307.
266.
V. B. Romakh, M. V. Kirillova, L. S. Shul’pina, J. J. R.
Fraústo da Silva, A. J. L. Pombeiro, G. B. Shul’pin, “The mechanism
of oxidation with hydrogen peroxide catalyzed by vanadate or
vanadtrane and PCA”, Abstracts of the 16th International
Symposium on Homogeneous Catalysis, Florence, Italy, 2008, P152.
267.
L. S. Shul’pina, M. V. Kirillova, A. M. Kirillov, A. J. L.
Pombeiro, Y. N. Kozlov, G. B. Shul’pin, “Hydrogen peroxide oxidation
of alkanes to alkyl hydroperoxides catalyzed by copper complexes”,
Abstracts of the 16th International Symposium on Homogeneous
Catalysis, Florence, Italy, 2008, P154.
268.
G. B. Shul’pin, A. R. Kudinov, L. S. Shul’pina, D. V.
Muratov, “Hydrogen peroxide oxidation of benzene catalyzed by
rhodium carbonyl cluster Rh6(CO)16”,
Abstracts of the 16th International Symposium on Homogeneous
Catalysis, Florence, Italy, 2008, P229.
269.
G. B. Shul’pin, Y. N. Kozlov, L. S. Shul’pina, K. C.
Chiacchio, D. Mandelli, “Oxidation of hydrocarbons with H2O2
catalyzed by solid and soluble aluminum-containing compounds”,
Abstracts of the 16th International Symposium on Homogeneous
Catalysis, Florence, Italy, 2008, P231.
270.
L. S. Shul’pina, L. P. Gabriel, A. R. Kudinov, D. Mandelli,
G. B. Shul’pin, “Osmium complexes as catalysts for oxygenation of
hydrocarbons with peroxides”, Abstracts of the 21st
Ibero-American Symposium of Catalysis, Málaga, Spain, 2008,
poster LT5-P47, page 156.
271.
D. Mandelli, W. A. Carvalho, Y. N. Kozlov, A. C. N. do
Amaral, R. Bogarin, K. C. Chiacchio, G. B. Shul’pin, “Oxidation
of alkanes and olefins with hydrogen peroxide catalyzed by aluminum
derivatives”, Abstracts of the 21st Ibero-American Symposium of
Catalysis, Málaga, Spain, 2008, oral presentation LT5-O35-S27,
page 136.
272.
D. Mandelli, K. C. Chiacchio, Y. N. Kozlov, G. B. Shul’pin,
“Hydrogen peroxide oxidation of hydrocarbons catalyzed by
Al-containing compounds: an accelerating effect of acids”,
Abstracts
of the 6th World Congress on Oxidation Catalysis,
Lille, France, 2009,
oral
presentation O73-1B, vol. O, page 212.
273.
A. J. Bonon, D. Mandelli, O. A. Kholdeeva, M. V. Barmatova,
Y. N. Kozlov, G. B. Shul’pin, “Oxidation of alkanes and olefins with
H2O2 in acetonitrile catalyzed by mesoporous
titanium-silicate Ti-MMM-2”, Abstracts of the 6th World Congress
on Oxidation Catalysis, Lille, France, 2009, poster 1B-P192,
vol. A, page 112.
274.
D. Mandelli, L. S. Shul’pina, M. K. G. Bizarra, G. B. Shul’pin,
“Oxidation of alcohols with molecular oxygen or air catalyzed
by FeCl3 and other iron compounds under visible light
irradiation”, Abstracts of the 6th World Congress on Oxidation
Catalysis, Lille, France, 2009, poster 2A-P666, vol. A, page
200.
275.
W. A. Carvalho, A. C. N. do Amaral, K. C. Chiacchio, D.
Mandelli, Y. N. Kozlov, G. B. Shul’pin, “Aluminum-catalyzed
oxidation of alkanes with H2O2: remarkable
accelerating effects of added acids or FeCl3”,
Proceedings of the International Conference EuropaCat IX “Catalysis
for a Sustainable World”, Salamanca, Spain, 2009, poster, page
279.
Publications on the
Chemistry Preprint Server (http://www.sciencedirect.com/preprintarchive
)
276.
G. B. Shul’pin, "Alkane oxidation:
estimation of alkyl hydroperoxide content by GC analysis of the
reaction solution samples before and after reduction with
triphenylphosphine", Chemistry Preprint
Archive, Volume 2001, Issue 6, June
2001, Pages 21–26.
277.
Y. N. Kozlov,
G. B. Shul’pin, "Can
methane and other alkanes be oxidized in solutions at low
temperature via a classical radical-chain mechanism?",
Chemistry Preprint Archive,
Volume 2001, Issue 6, June 2001, Pages 57–65.
278.
Y. N. Kozlov,
G. B. Shul’pin, "Alkane
oxidation with participation of hydroxyl radicals from H2O2.
A comparison of V- and Fe-based catalytic systems",
Chemistry Preprint Archive,
Volume 2001, Issue 6, June 2001, Pages 70–76.
279.
G. B. Shul’pin, "Alkane oxygenation with hydrogen peroxide
catalysed by soluble derivatives of nickel and platinum",
Chemistry Preprint Archive, Volume 2002, Issue 4, April 2002,
Pages 8–12.
280.
G. B. Shul’pin, E. R. Lachter, "Aerobic hydroxylation of
hydrocarbons catalysed by vanadate ion", Chemistry Preprint
Archive, Volume 2002, Issue 4, April 2002, Pages 13–17.
281.
G. B. Shul’pin, G. V. Nizova, Y. N. Kozlov , I. G. Pechenkina,
"Catalase and oxygenase activities of a dinuclear manganese(IV)
1,4,7-trimethyl-1,4,7-triazacyclononane complex in the reaction with
H2O2 and an alkane", Chemistry Preprint
Archive, Volume 2002, Issue 4, April 2002, Pages 18–34.
282.
G. V. Nizova, B. Krebs, G. Süss-Fink, S. Schindler, L.
Westerheide, L. Gonzalez Cuervo, G. B. Shul’pin, "Oxidation of
saturated hydrocarbons with H2O2 catalysed by
a dinuclear iron complex and an amino acid", Chemistry Preprint
Archive, Volume 2002, Issue 5, May 2002, Pages 33–44.
283.
M. H. C. de la Cruz, Y. N. Kozlov, E. R. Lachter, G. B.
Shul’pin, "Kinetics and mechanism of the benzene hydroxylation by
the O2-H2O2-vanadium
derivative-pyrazine-2-carboxylic acid reagent", Chemistry
Preprint Archive, Volume 2002, Issue 5, May 2002, Pages 45–53.
284.
G. B. Shul’pin, "Metal-catalyzed hydrocarbon oxidations",
Chemistry Preprint Archive, Volume 2003, Issue 4, April 2003,
Pages 181-198.
285.
G. B. Shul’pin, J. Gradinaru, "Efficient alkane
hydroperoxidation with peroxides catalysed by copper complexes",
Chemistry Preprint Archive, Volume 2003, Issue 4, April 2003,
Pages 199–212.
286.
G. B. Shul’pin, Y. N. Kozlov, "Kinetics and mechanism of
alkane hydroperoxidation with tert-butyl hydroperoxide catalysed by
vanadate anion", Chemistry Preprint Archive, Volume 2003,
Issue 4, April 2003, Pages 213–220.
287.
G. B. Shul’pin, Y. N. Kozlov, L. Cuervo Gonzalez , G. Süss-Fink,
"Oxidation of alkanes including methane and ethane with peroxyacetic
acid catalysed by vanadium complexes", Chemistry Preprint Archive,
Volume 2003, Issue 11, November 2003, Pages 45–63.
288.
G. B. Shul’pin, H. Stoeckli-Evans, D. Mandelli, Y. N. Kozlov,
A. T. Vallina, C. B. Woitiski, R. S. Jimenez, W. A. Carvalho,
"Oxidation of alkanes with m-chloroperbenzoic acid catalyzed by
iron(III) chloride and a polydentate amine", Chemistry Preprint
Archive, Volume 2004, Issue 2, February 2004, Pages 1–14.
289.
C. B. Woitiski, Y. N. Kozlov, D.
Mandelli, G. V. Nizova, U. Schuchardt, G. B. Shul’pin, "Oxidations
by the system “hydrogen peroxide-dinuclear manganese (IV)
complex-carboxylic acid”. Part 5. Epoxidation of olefins including
natural terpenes", Chemistry Preprint
Archive, Volume 2004, Issue 2,
February 2004, Pages 31–60.
290.
D. Mandelli, R. A. Steffen,
G. B. Shul’pin, "Carvone
epoxidation by the ‘hydrogen peroxide-manganese (IV) complex-oxalic
acid’ system in acetonitrile: a combinatorial approach to the
process optimization", Chemistry
Preprint Archive, Volume 2004, Issue
2, February 2004, Pages 81–87.
291.
G. V. Nizova, V. S. Arutyunov, Y.
N. Kozlov, G. B. Shul’pin, "Oxidation
of alkanes including methane by the ‘hydrogen peroxide–manganese(IV)
complex–oxalic acid’ system in water: unusual regio-selectivity in
the reaction with n-heptane",
Chemistry Preprint Archive, Volume
2004, Issue 2, February 2004, Pages 154–165.
292.
V. A. dos Santos, D. Mandelli, M.
I. F. Barbosa, G. B. Shul’pin, "Highly
Efficient Oxidation of Alcohols with H2O2
Catalyzed by a Dinuclear Manganese(IV) Complex and Oxalic Acid",
Chemistry Preprint Archive,
Volume 2004, Issue 5, May 2004, Pages 19–25.
293.
D. Mandelli, A. C. M. dos Santos,
A. C. T. Ferreira, G. B. Shul’pin, "Epoxidation
of Dec-1-ene with H2O2 in Water Catalyzed by a
Dinuclear Manganese(IV) Complex and Oxalic Acid: the Dramatic Role
of Added Acetonitrile", Chemistry Preprint Archive, Volume
2004, Issue 5, May 2004, Pages 59–63.
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